Massachusetts Institute of Technology
Department of Chemical Engineering

The Investigation of the Contamination of Indoor Air by Fume Hood Exhausts

Chemical Engineering Laboratory Fall, 1994
Consultants: Adel F. Sarofim (ext 3-4566), Anthony
Modestino (ext 3-6556, Chemical Engineering
Department; Dr. C. Billings (3-5360), L. Di
Berardinis (3-2596), M.l.T. Environmental
Medicine Service


Statement of the Project

University campuses have large numbers of fume hoods that are designed to dilute and disperse potentially harmful chemicals. In a campus where the buildings are in close proximity there is a possibility that the exhausts from the ume hoods from one building can be drawn into the air intake ducts of another. The problem is difficult to analyze because of the complex air flow patterns over buildings. Depending on the meteorological conditions downdrafts can occur which bring the exhaust from the stacks down to ground level, a problem that can be aggravated on a hot summer day when the plume from the exhaust from an air conditioned building can be denser than the ambient air. Estimations of the plume trajectories and exhaust dilution are made difficult by the complex flow patterns around and between buildings (You must have experienced the acceleration of the flow under the Green Building and the swirling motions on the North side of the passage connecting Buildings 56 and 66). It is because of such complexities that tracers are used to determine the fate of contaminants.

One tracer that is commonly used is sulfur hexafluoride. It has the advantages of being gaseous, chemically inert, non-toxic, insoluble in water and detectable at very low concentration. A gas chromatograph with an electron capture detector can pick up one part of sulfur hexafluoride in 1012 parts of air. It has been used in tracer studies (P. Drivas, Ph.D. Thesis, California Institute of Technology, 1975)to study the ventilation systems in buildings, airflow within the wake downwind of a building, dispersion of from an urban highway, and large- scale transport and dispersion over the Los Angeles area. As a measure of the sensitivity of the technique SF6 released in Anaheim was monitored over 100 kilometers away in Palm Springs. One of the interesting results by Drivas was that in one experiment at Caltech 20 percent of the fumes exhausted by a roof fume hood were found to reenter the ventilation system through the main ventilation intake located only 16 feet away!

The project is to


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