5.05 “Main Group Chemistry”

A graduate subject in the inorganic chemistry program @MIT

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Contact

Phone: (617) 253-5332

Email: ccummins@mit.edu

  • "Amazing molecules of main group chemistry"
  • "Rings and cages"

Readings

Readings for 5.05 include recommended books and journal articles, journal special issues devoted to main group chemistry, and computational chemistry resource manuals. Proficiency will be assessed with occasional in-class quizzes and a year-end project.

Books

  • The Chemical Bond
  • Modern aspects of main group chemistry
  • Discovering chemistry with natural bond orbitals
  • Atoms in molecules: an introduction

Some Key Articles

  • Natural bond orbital methods
  • The ORCA program system
  • Molecular double-bond covalent radii for elements Li-E112
  • Dative bonds in main-group compounds: a case for fewer arrows
  • What is a hydrogen bond? (E2PERT)
  • How to write a paper by George Whitesides

Themed Issues

  • Frontiers in Main Group Chemistry (Chem. Rev. 2019).
  • NHCs in Main Group Chemistry (Chem. Rev. 2019).
  • Chem. Soc. Rev. Modern Main Group Chemistry issue
  • Forum on main group chemistry from synthesis to applications
  • Applications of electrophilic main group organometallic molecules
  • Frustrated Lewis Pairs
  • The renaissance of main group chemistry
  • Main group chemistry: from molecules to materials

Videos

  • Lecture on Atoms in Molecules theory by Richard Bader


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