Harvard Applied Mechanics Colloquium Wednesday, April 21, 2004 Title: A Theory of Cooperative Diffusion in Dense Granular Flows Speaker: Martin Z. Bazant (MIT, Applied Math) Abstract: Dilute granular flows are routinely described by the kinetic theory of (inelastic) gases and classical hydrodynamics, but dense flows require a fundamentally different approach, due to long-lasting, many-body contacts. In the case of silo drainage, many continuum models have been proposed for the mean flow, but no statistical theory is available. Here, we propose that particles undergo cooperative random motion in diffusing ``spots'' of free volume, extending across several particle diameters. The continuum limit of the Spot Model provides new, non-local partial differential equations for tracer diffusion in dense flows. The theory directly relates diffusion and cage-breaking to volume fluctuations, in agreement with particle-tracking experiments in the MIT Dry Fluids Lab. It also provides a simple explanation of density waves, caused by weak short-ranged repulsion between spots. Direct evidence for spots comes from our observation of spatial velocity correlations in experimental and computational flows. The basic idea of a spot of cooperative diffusion may also apply to other dense, disordered materials, such as metallic glasses.