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2000

SLB # Authors Title Journal Reference

188.

Wolfe, J.P.; Buchwald, S.L.

Palladium-Catalyzed Amination of Aryl Halides and Aryl Triflates: N-Hexyl-2-methyl-4-methoxy Aniline and N-Methyl-N-(4-Chlorophenyl) Aniline

Org. Syn. 2000, 78, 23

178.

Torraca, K.E.; Kuwabe, S.-I.; Buchwald, S.L.

A High-Yield, General Method for the Catalytic Formation of Oxygen Heterocycles

J. Am. Chem. Soc. 2000, 122, 12907

177.

Yin, J.; Buchwald, S.L.

A Catalytic Asymmetric Suzuki Coupling for the Synthesis of Axially Chiral Biaryl Compounds

J. Am. Chem. Soc. 2000, 122, 12051

176.

Zhang, X.-X.; Buchwald, S.L.

Efficient Synthesis of N-Aryl-Aza-Crown Ethers via Palladium-Catalyzed Amination

J. Org. Chem. 2000, 65, 8027

175.

Tomori, H.; Fox, J.M.; Buchwald, S.L.

An Improved Synthesis of Functionalized Biphenyl-based Phosphine Ligands

J. Org. Chem. 2000, 65, 5334

174.

Zhang, X.-X.; Sadighi, J.P.; Mackewitz, T.W.; Buchwald, S.L.

Efficient Synthesis of Well-Defined, High Molecular Weight and Processible Polyanilines Under Mild Conditions via Palladium-Catalyzed Amination

J. Am. Chem. Soc. 2000, 122, 7606

173.

Moritani, Y.; Appella, D.H.; Jurkauskas, V.; Buchwald, S.L.

Synthesis of β-Alkyl Cyclopentanones in High Enantiomeric Excess via Copper-Catalyzed Asymmetric Conjugate Reduction

J. Am. Chem. Soc. 2000, 122, 6797

172.

Plante, O.; Buchwald, S.L.; Seeberger, P. H.

Easily Removable Substituted Benzyl Ethers: Novel Protecting Groups for Oligosaccharide Synthesis

J. Am. Chem. Soc. 2000, 122, 7148

171.

Harris, M.; Buchwald, S.L.

One-Pot Synthesis of Unsymmetrical Triarylamines From Aniline Precursors

J. Org. Chem. 2000, 65, 5327

170.

Hundertmark, T.; Littke, A.F.; Buchwald, S.L.; Fu, G.C.

Pd(PhCN)2Cl2/P(t-Bu)3: A Versatile Catalyst for Sonogashira Reactions of Aryl Bromides at Room Temperature

Org. Lett. 2000, 2, 1729

169.

Old, D.W.; Harris, M.C.; Buchwald, S.L.

The Efficient Palladium-Catalyzed N-Arylation of Indoles

Org. Lett. 2000, 2, 1403

168.

Yin, J.; Buchwald, S.L.

Palladium-Catalyzed Intermolecular Coupling of Aryl Halides and Amides

Org. Lett. 2000, 2, 1101

167.

Hansen, M.C.; Buchwald, S.L.

A Method for the Asymmetric Hydrosilylation of N-Aryl Imines

Org. Lett. 2000, 2, 713

166.

Yun, J.; Buchwald, S.L.

Kinetic Resolution and Isomerization of 2,5-Disubstituted Pyrrolines

Chirality 2000, 12, 476

165.

Fox, J.M.; Huang, X.; Chieffi, A.; Buchwald, S.L.

Highly Active and Selective Catalysts for the Formation of α-Arylketones

J. Am. Chem. Soc. 2000, 122, 1360

164.

Yun, J.; Buchwald, S.L.

Efficient Kinetic Resolution in the Asymmetric Hydrosilylation of Imines of 3-Substituted Indanones and 4-Substituted Tetralones

J. Org. Chem. 2000, 65, 767

163.

Wolfe, J.P.; Buchwald, S.L.

Scope and Limitations of the Pd/BINAP-Catalyzed Amination of Aryl Bromides

J. Org. Chem. 2000, 65, 1144

162.

Wolfe, J.P.; Tomori, H.; Yin, J.; Sadighi, J.; Buchwald, S.L.

A Simple, Efficient Catalyst System for the Palladium-Catalyzed Amination of Aryl Chlorides, Bromides, and Triflates

J. Org. Chem. 2000, 65, 1158

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1999

SLB # Authors Title Journal Reference

161.

Appella, D.H.; Moritani, Y.; Shintani, R.; Ferreira, E.; Buchwald, S.L.

Asymmetric Conjugate Reduction of α,β-Unsaturated Esters Using a Chiral Phosphine-Copper Catalyst

J. Am. Chem. Soc. 1999, 121, 9473

160.

Wagaw, S.; Yang, B.H.; Buchwald, S.L.

A Palladium-Catalyzed Method for the Preparation of Indoles via the Fischer Indole Synthesis

J. Am. Chem. Soc. 1999, 121, 10251

159.

Frid, M.; Pérez, D.; Peat A.J.; Buchwald, S.L.

A Combined Zirconocene Benzyne, Palladium Cross-Coupling Route to Substituted Biphenyls and Terphenyls

J. Am. Chem. Soc. 1999, 121, 9469

158.

Wolfe, J.P.; Singer, R.A.; Yang, B.H.; Buchwald, S.L.

Highly Active Palladium Catalysts for Suzuki Coupling Reactions

J. Am. Chem. Soc. 1999, 121, 9550

157.

Gürtler, C.; Buchwald, S.L.

A Phosphine-Free Catalyst System for the Heck Arylation of Disubstituted Alkenes: Application to the Synthesis of Trisubstituted Olefins

Chemistry-A European Journal 1999, 5, 3107

156.

Harris, M.C.; Geis, O.; Buchwald, S.L.

Sequential N-Arylation of Primary Amines as a Route to Alkyldiarylamines

J. Org. Chem. 1999, 64, 6019

155.

Hicks, F.A.; Buchwald, S.L.

An Intramolecular Titanium-Catalyzed Asymmetric Pauson-Khand Type Reaction

J. Am. Chem. Soc. 1999, 121, 7026

154.

Wolfe, J.P.; Buchwald, S.L.

A Highly Active Catalyst for the Room Temperature Catalytic Amination and Suzuki Coupling of Aryl Chlorides

Angew. Chemie Int. Ed. 1999, 38, 2413

153.

Sturla, S.J.; Buchwald, S.L.

Catalytic Asymmetric Cyclocarbonylation of Nitrogen-Containing Enynes

J. Org. Chem. 1999, 64, 5547

152.

Yun, J.; Buchwald, S.L.

Titanocene-Catalyzed Asymmetric Ketone Hydrosilylation: The Effect of Catalyst Activation Protocol and Additives on the Reaction Rate and Enantioselectivity

J. Am. Chem. Soc. 1999, 121, 5640

151.

Yang, B.H.; Buchwald, S.L.

The Development of Efficient Protocols for the Palladium-Catalyzed Cyclization Reactions of Secondary Amides and Carbamates

Org. Lett. 1999, 1, 35

150.

Hicks, F.A.; Kablaoui, N.M.; Buchwald, S.L.

The Scope of the Intramolecular Titanocene-Catalyzed Pauson-Khand Type Reaction

J. Am. Chem. Soc. 1999, 121, 5881

149.

Troutman, M.V.; Appella, D.H.; Buchwald, S.L.

Asymmetric Hydrogenation of Unfunctionalized Tetrasubstituted Olefins with a Cationic Zirconocene Catalyst

J. Am. Chem. Soc. 1999, 121, 4916

148.

Aranyos, A.; Old, D.W.; Wolfe, J.P.; Kiyomori, A.; Sadighi, J.P.; Buchwald, S.L.

Novel Electron-Rich Bulky Phosphine Ligands Facilitate the Palladium-Catalyzed Preparation of Diaryl Ethers

J. Am. Chem. Soc. 1999, 121, 4369

147.

Kiyomori, A.; Marcoux, J.-F.; Buchwald, S.L.

An Efficient Copper-Catalyzed Coupling of Aryl Halides with Imidazoles

Tetrahedron Lett. 1999, 40, 2657

146.

Hansen, M.C.; Buchwald, S.L.

Synthesis of NPS R-568 Utilizing Titanium-Catalyzed Asymmetric Hydrosilylation

Tetrahedron Lett. 1999, 40, 2033

145.

Sturla, S.J.; Kablaoui, N.M.; Buchwald, S.L.

A Titanocene-Catalyzed Intramolecular Ene Reaction: Cycloisomerization of Enynes and Dienynes

J. Am. Chem. Soc. 1999, 121, 1976

144.

Singer, R.A.; Buchwald, S.L.

Preparation of 2-Amino-2'-hydroxy-1,1'-binaphthyl and N-arylated 2-amino-1,1'-binaphthyl Derivatives via Palladium-Catalyzed Amination

Tetrahedron Lett. 1999, 40, 1095

143.

Yang, B.H.; Buchwald, S.L.

Palladium-Catalyzed Amination of Aryl Halides and Sulfonates

J. Organomet. Chem. 1999, 576, 125

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