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2008

SLB # Authors Title Journal Reference
312 Martin, R. and Buchwald, S.L. An Improved Protocol for the Pd-Catalyzed a-Arylation of Aldehydes with Aryl Halides.

Org. Lett. 2008, 10, 4561-4564

311 Fors, B.P.; Watson, D.A.; Biscoe, M.R. and Buchwald, S.L. A Highly Active Catalyst for Pd-Catalyzed Amination Reactions:  Cross-Coupling Reactions Using Aryl Mesylates and the Highly Selective Monoarylation of Primary Amines.

J. Am. Chem. Soc. 2008, 130, 13552-13554

310 Garcia-Fortanet, J. and Buchwald, S.L. Asymmetric Palladium-Catalyzed Intramolecular a-Arylation of Aldehydes. Angew. Chem. Int. Ed. 2008, 47, 8108-8111
309 Tsang, W.C.P.; Munday, R.H.; Brasche, G.; Zheng, N. and Buchwald, S.L. A Palladium-Catalyzed Method for the Synthesis of Carbazoles via Tandem C-H Functionalization and C-N Bond Formation. J. Org. Chem. 2008, 73, 7603-7610
308 Martinelli, J.R.; Watson, D.A.; Freckmann, D.M.M.; Barder, T.E. and Buchwald, S.L.  Palladium-Catalyzed Carbonylation Reactions of Aryl Bromides at Atmospheric Pressure: A General System Based on Xantphos.

J. Org. Chem. 2008, 73, 7102-7107

307 Fors, B.P., Krattiger, P.; Strieter, E. and Buchwald, S.L. Water-Mediated Preactivation:  An Efficient Protocol for C-N Cross-Coupling Reactions.

Org. Lett. 2008, 10, 3505-3508

306 Watson, D.A.; Fan, X.; Buchwald, S.L. Carbonylation of Aryl Chlorides with Oxygen Nucleophiles at Atmospheric Pressure. Preparation of Phenyl Esters as Acyl Transfer Agents, and the Direct Preparation of Alkyl Esters and Carboxylic Acids.

J. Org. Chem. 2008, 73, 7096-7101

305 Altman, R.A.; Hyde, A.M.; Huang, X. and Buchwald, S.L. Orthogonal Pd- and Cu-Based Catalyst Systems for C- and N-Arylation of Oxindoles.

J. Am. Chem. Soc. 2008, 130, 9613-9620

304 Altman, R.A.; Anderson, K. W. and Buchwald, S.L.  Pyrrole-2-Carboxylic Acid as a Ligand for the Cu-Catalyzed Reactions of Primary Anilines with Aryl Halides.

J. Org. Chem. 2008, 73, 5167-5169

303 Wang, H.; Duennwald, M. L.; Roberts, B. E.; Rozeboom, L. M.; Zhang, Y. L.; Steele, A. D.; Krishnan, R.; Su, L. J.; Griffin D.; Mukhopadhyay, S.; Hennessy, E. J.; Weigele, P.; Blanchard, B. J.; King, J.; Deniz, A. A.; Buchwald, S. L.; Ingram, V. M.; Lindquist, S. and Shorter, J. Direct and Selective Elimination of Speciofic Prions and Amyloids by 4,5-Dianilinophthalimide and Analogs.

Proc. Natl. Acad. Sci. U.S.A. 2008, 105, 7159-7164

302 Billingsley, K.L. and Buchwald, S.L. An Improved System for the Palladium-Catalyzed Borylation of Aryl Halides with Pinacol Borane. J. Org. Chem. 2008, 73, 5589-5591
301 Minatti, A.E.  and Buchwald, S. L.   Synthesis of Indolines via a Domino Cu-Catalyzed Amidation/Cyclization Reaction.

Org. Lett. 2008, 10, 2721-2724

300 Martin, R. and Buchwald, S.L.  Palladium-Catalyzed Suzuki-Miyaura Cross-coupling Reactions Employing Dialkylbiaryl Phosphine Ligands. Acc. Chem. Res. 2008, 41, 1461-1473
299 Billingsley, K.L. and Buchwald, S.L. A General and Efficient Method for the Suzuki-Miyaura Coupling of 2-Pyridyl Nucleophiles. Angew. Chem. Int. Ed. 2008, 47, 4695-4698
298 Brasche, G.; Garcia-Fortanet, J. and Buchwald, S.L.  Twofold C-H Functionalization: Palladium-catalyzed ortho Arylation of Anilides.

Org. Lett. 2008, 10, 2207-2210

297 Biscoe, M.R.; Fors, B.P. and  Buchwald, S.L.  A New Class of Easily Activated Palladium Precatalysts for Facile C–N Cross-Coupling Reactions and Low Temperature Oxidative Additions of Aryl Chlorides.

J. Am. Chem. Soc. 2008, 130, 6686-6687

296 Surry, D.S. and Buchwald, S.L. Biaryl Phosphane Ligands in Palladium-Catalyzed Amination.

Angew. Chem. Int. Ed. 2008, 47, 6338-6361

295 Naber, J. R. and Buchwald, S.L.  Palladium-Catalyzed Stille Cross-Coupling Reaction of Aryl Chlorides using a Pre-Milled Palladium Acetate and XPhos Catalyst System.

Adv. Syn. Cat. 2008, 350, 957-961

294 Munday, R.H.; Martinelli, J.R.;  and Buchwald, S.L. Palladium-Catalyzed Carbonylation of Aryl Tosylates and Mesylates.

J. Am. Chem. Soc. 2008, 130, 2754-2755

293 Brasche, G. and Buchwald, S.L. C-H Functionalization/C-N Bond Formation: Copper-Catalyzed Synthesis of Benzimidazoles from Amidines.

Angew. Chem. Int. Ed. 2008, 47,1932-1934

290 Altman, R.A.; Shafir, A.; Choi, A.; Lichtor, P.A.; Buchwald, S.L. An Improved Cu-Based Catalyst System for the Reactions of Alcohols with Aryl Halides

J. Org. Chem. 2008, 73, 284-286

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2007

SLB # Authors Title Journal Reference
292 Martin, R.; Cuenca, A.; Buchwald, S.L. Sequential Copper-catalyzed Vinylation/Cyclization: An Efficient Synthesis of Functionalized Oxazoles

Org. Lett. 2007, 9, 5521-5524

291 Hyde, A.M.; Buchwald, S.L. Palladium-Catalyzed g-Arylation of b,g-Unsaturated Ketones: Application to a One-Pot Synthesis of Tricyclic Indolines

Angew. Chem. Int. Ed. 2007, 47, 177-180

289 Zheng, N.; Buchwald, S.L. A Copper-Catalyzed Regiospecfic Synthesis of N-Alkyl Benzimidazoles

Org. Lett. 2007, 9, 4749-4751

288 Altman, R.A.; Fors, B.P.; Buchwald, S.L. Pd-Catalyzed Amination Reactions of Aryl Halides Using Bulky Biarylmonophosphine Ligands

Nature Protocols 2007, 2, 2881-2887

287

Altman, R.A.; Buchwald, S.L.

Pd-Catalyzed Suzuki-Miyaura Reactions of Aryl Halides Using Bulky Biarylmonophosphine Ligands

Nature Protocols 2007, 2, 3115-3121

286 Minatti, A.E.; Zheng, X.; Buchwald, S.L. Synthesis of Chiral 3-Substituted Indanones via an Enantioselective Reductive-Heck Reaction

J. Org. Chem. 2007, 72, 9253-9258

285 Ikawa, T.; Barder, T.E.; Biscoe, M.R.; Buchwald, S.L. Pd-Catalyzed Amidations of Aryl Chlorides Using Monodentate Biaryl Phosphine Ligands:  A Kinetic, Computational, and Synthetic Investigation

J. Am. Chem. Soc. 2007, 129, 13001-13007

284 Altman, R.A.; Buchwald, S.L. Cu-Catalyzed Goldberg and Ullmann Reactions of Aryl Halides Using Chelating N- and O-Based Ligands

Nature Protocols 2007, 2, 2474-2479

283 Martinelli, J.R.; Clark, T.P.; Watson, D.A.; Munday, R.H.; Buchwald, S.L. Palladium-Catalyzed Aminocarbonylation of Aryl Chlorides at Atmospheric Pressure: the Dual Role of Sodium Phenoxide

Angew. Chem. Int. Ed. 2007, 46, 8460-8463

282 Martin, R.; Buchwald, S.L. A General Method for the Direct a-Arylation of Aldehydes with Aryl Bromides and Chlorides

Angew. Chem. Int. Ed. 2007, 46, 7236-7239

281 Jones, C.P.; Anderson, K.W.; Buchwald, S.L. Sequential Cu-Catalyzed Amidation-Base-mediated Camps Cyclization: A Two-step Synthesis of 2-Aryl-4-quinolones from ortho-Halophenones

J. Org. Chem. 2007, 72, 7968-7973

280 McNeill, E.; Barder, T.E.; Buchwald, S.L. Palladium-Catalyzed Silylation of Aryl Chlorides with Hexamethyldisilane

Org. Lett. 2007, 9, 3785-3788

279 Zheng, N.; Anderson, K.W.; Huang, X.; Nguyen, H.N.; Buchwald, S.L. A Palladium-Catalyzed Regiospecific Synthesis of N-Aryl Benzimidazoles

Angew. Chem. Int. Ed. 2007, 46, 7509-7512

278 Barder, T.E.; Buchwald, S.L. Insights into Amine Binding to Biaryl Phosphine Palladium Oxidative Addition Complexes and Reductive Elimination from Biaryl Phosphine Arylpalladium Amido Complexes via Density Functional Theory

J. Am. Chem. Soc. 2007, 129, 12003-12010

277 Surry, D.S.; Buchwald, S.L.  Selective Palladium-Catalyzed Arylation of Ammonia: Synthesis of Anilines as well as Symmetrical and Unsymmetrical Di- and Triarylamines

J. Am. Chem. Soc. 2007, 129, 10354-10355

276 Martin, R.; Larsen, C.H.; Cuenca, A.; Buchwald, S.L. Cu-catalyzed Tandem C–N Bond Formation for the Synthesis of Pyrroles and Heteroarylpyrroles

Org. Lett. 2007, 9, 3379-3382

275 Biscoe, M. R.; Barder, T.E.; Buchwald, S.L. Electronic Effects on the Selectivity of Pd-Catalyzed C-N Bond-Forming Reactions Using Biarylphospine Ligands:  The Competitive Roles of Amine Binding and Acidity Angew. Chem., Int. Ed. 2007, 46, 7232-7235
274 Altman, R. A.; Koval, E.D.; Buchwald, S.L. The Copper-Catalyzed N-Arylation of Imidazoles and Benzimidazoles J. Org. Chem. 2007, 72, 6190-6199
273 Billingsley, K.; Barder, T.E.; Buchwald, S.L.  Palladium-Catalyzed Borylation of Aryl Chlorides: Scope, Applications and Computational Studies Angew. Chem., Int. Ed. 2007, 46, 5359-5363

272

Martin, R.; Buchwald, S.L.

Pd-catalyzed Kumada-Corriu Cross-Coupling Reactions at Low Temperatures Allow the use of Knochel-type Grignard Reagents

J. Am. Chem. Soc. 2007, 129, 3844-3845

271

Shafir, A.; Lichtor, P.A.; Buchwald, S.L.

N- vs. O-Arylation of Aminoalcohols: Orthogonal Selectivity in Copper-Based Catalysts

J. Am. Chem. Soc. 2007, 129, 3490-3491

270

Rodriguez Rivero, M.; Buchwald, S.L.

Copper-Catalyzed Vinylation of Hydrazides. A Regioselective Entry to Highly-Substituted Pyrroles

Org. Lett. 2007, 9, 973-976

269

Altman, R. A.; Buchwald, S.L.

Cu-Catalyzed N- and O-Arylation of 2-, 3- and 4-Hydroxypyridines and Hydroxyquinolines

Org. Lett. 2007, 9, 643-646

268

Billingsley, K.; Buchwald, S.L.

Highly Efficient Monophosphine-Based Catalyst for the Palladium-Catalyzed Suzuki-Miyaura Reaction of Heteroaryl Halides and Heteroaryl Boronic Acids and Esters

J. Am. Chem. Soc. 2007, 129, 3358-3366

267

Barder, T.E.; Buchwald, S.L.

Rationale Behind the Resistance of Dialkylbiaryl Phosphines Toward Oxidation by Molecular Oxygen

J. Am. Chem. Soc. 2007, 129, 5096-5101

266

Barder, T.E.; Biscoe, M.R.; Buchwald, S.L

Structural Insights into Active Catalyst Structures, Oxidative Addition and Amine Binding to Biaryl Phosphine-Palladium Complexes via Density Functional Theory and Experimental Studies

Organometallics 2007, 26, 2183-2192

265

Barder, T.E.; Buchwald, S.L.

Benchtop Monitoring of Reaction Progress via Reversible Fluorescent Sensors by a Handheld UV Lamp:  In Situ Sensing of Boronic Acids in the Suzuki-Miyaura Reaction

Org. Lett. 2007, 9 ,137-139

264

Murphy, E.R.; Martinelli, J.R.; Zaborenko, N.; Buchwald, S.L.; Jensen, K.F.

Accelerating Reactions with Microreactors at Elevated Temperatures and Pressures:  Profiling Aminocarbonlation Reactions

Angew. Chem., Int. Ed. 2007, 46, 1734-1737

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