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2010

SLB # 1 Authors Title Journal Reference and DOI Link
  Fors, B.P., and Buchwald, S.L. Commentary on “A New, Efficient and Recyclable Lanthanum(III) Oxide-Catalyzed CN Cross-Coupling” by S. Narayana Murthy, B. Madhav, V. Prakash Reddy, and Y. V. D. Nageswar, Adv. Synth. Catal. 2010, 352, 3241–3245 Adv. Synth. Catal. 2010, 352, 3119-3120
348 Fors, B.P., and Buchwald, S.L. A Multiligand Based Pd Catalyst for C–N Cross-Coupling Reactions J. Am. Chem. Soc. 2010, 132, 15914-15917
347 Naber, J. R., and Buchwald, S.L. Packed-Bed Reactors for Continuous-Flow C–N Cross-Coupling Angew. Chem. Int. Ed. 2010, 49, 9469-9474
346 Henderson, J.L., and Buchwald, S.L. Efficient Pd-Catalyzed Amination Reactions for Heterocycle Functionalization Org. Lett. 2010, 12, 4442-4445
345 Henderson, J.L., McDermott, S.M., and Buchwald, S.L. Palladium-Catalyzed Amination of Unprotected Halo-7-azaindoles Org. Lett. 2010, 12, 4438-4441
344 Shen, X., Hyde, A.M., and Buchwald, S.L. Palladium-Catalyzed Conversion of Aryl and Vinyl Triflates to Bromides and Chlorides J. Am. Chem. Soc. 2010, 132, 14076-14078
343 Tsvelikhovsky, D., and Buchwald, S.L. Synthesis of Heterocycles via Pd-Ligand Controlled Cyclization of 2-Chloro-N-(2-vinyl)aniline: Preparation of Carbazoles, Indoles, Dibenzazepines, and Acridine J. Am. Chem. Soc. 2010, 132, 14048-14051
342 Kinzel, T., Zhang, Y., and Buchwald, S.L. A New Palladium Precatalyst Allows for the Fast Suzuki−Miyaura Coupling Reactions of Unstable Polyfluorophenyl and 2-Heteroaryl Boronic Acids J. Am. Chem. Soc. 2010, 132, 14073-14075
341 Hartman, R.L., Naber, J.R., Zaborenko, N., Buchwald, S.L., and Jensen, K.F. Overcoming the Challenges of Solid Bridging and Constriction during Pd-Catalyzed C–N Bond Formation in Microreactors Org. Process Res. Dev. 2010, 14, 1347-1357
338 Maimone, T.J., and Buchwald, S.L. Pd-Catalyzed O-Arylation of Ethyl Acetohydroximate: Synthesis of
O
-Arylhydroxylamines and Substituted Benzofurans
J. Am. Chem. Soc. 2010, 132, 9990-9991
337 Shen, X., Jones, G.O., Watson, D.A., Bhayana, B., and Buchwald, S.L. Enantioselective Synthesis of Axially Chiral Biaryls by the Pd-Catalyzed Suzuki−Miyaura Reaction: Substrate Scope and Quantum Mechanical Investigations J. Am. Chem. Soc. 2010, 132, 11278-11287
336 McMullen, J.P., Stone, M.T., Buchwald, S.L., and Jensen, K.F. An Integrated Microreactor System for Self-Optimization of a Heck Reaction: From Micro- to Mesoscale Flow Systems Angew. Chem. Int. Ed. 2010, 49, 7076-7080
335 Cho, E.J., Senecal, T.D., Kinzel, T., Zhang, Y., Watson, D.A., and Buchwald, S.L. The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides Science 2010, 328, 1679-1681

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334 Dooleweerdt, K., Fors, B.P., and Buchwald, S.L. Pd-Catalyzed Cross-Coupling Reactions of Amides and Aryl Mesylates Org. Lett. 2010, 12, 2350-2353
333 Surry, D.S., and Buchwald, S.L. Diamine Ligands in Copper-Catalyzed Reactions Chem. Sci. 2010, 1, 13-31
332 Jones, G.O., Liu, P., Houk, K.N. and Buchwald, S.L. Computational Explorations of Mechanisms and Ligand-Directed Selectivities of Copper-Catalyzed Ullmann-Type Reactions J. Am. Chem. Soc. 2010, 132, 6205-6213
331 Maiti, D. and Buchwald, S.L. Cu-Catalyzed Arylation of Phenols: Synthesis of Sterically Hindered and Heteroaryl Diaryl Ethers J. Org. Chem. 2010, 75, 1791-1794
330 Hartman, R.L., Naber, J.R., Buchwald, S.L. and Jensen, K.F. Multistep Microchemical Synthesis Enabled by Microfluidic Distillation Angew. Chem. Int. Ed. 2010, 49, 899-903
329 Shen, X. and Buchwald, S.L. Rhodium-Catalyzed Asymmetric Intramolecular Hydroamination of Unactivated Alkenes Angew. Chem. Int. Ed. 2010, 49, 564-567
326 Naber, J.R., Fors, B.P., Wu, X., Gunn, J.T. and Buchwald, S.L. Stille Cross-Coupling Reactions of Aryl Mesylates and Tosylates Using a Biarylphosphine Based Catalyst System. Heterocycles 2010, 80, 1215-1226

2009

SLB # 1 Authors Title Journal Reference and DOI Link
328 Maiti, D. and Buchwald, S.L. Orthogonal Cu- and Pd-Based Catalyst Systems for the O and N-Arylation of Aminophenols. J. Am. Chem. Soc. 2009, 131, 17423-17429
327 Hicks, J.D., Hyde, A.M., Cuezva, A.C., and Buchwald, S.L. Pd-Catalyzed N-Arylation of Secondary Acyclic Amides: Catalyst Development, Scope, and Computational Study. J. Am. Chem. Soc. 2009, 131, 16720-16734
325 Fors, B.P. and Buchwald, S.L. The Pd-Catalyzed Conversion of Aryl Chlorides, Triflates, and Nonaflates to Nitroaromatics. J. Am. Chem. Soc. 2009, 131, 12898-12899
324 Bhayana, B.; Fors, B.P. and Buchwald, S.L. A Versatile Catalyst System for Suzuki-Miyaura Cross-Coupling Reactions of C(sp2)-Tosylates and Mesylates. Org. Lett. 2009,11, 3954-3957
323 Watson, D.A., Su, M., Teverovskiy, G., Zhang, Y., Garcia-Fortanet, J., Kinzel, T. and Buchwald, S.L. Reductive Elimination of ArF from a Pd(II) Complex:  Catalytic Conversion of Aryl Triflates to ArF. Science 2009, 325, 1661-1664
322 Buchwald, S.L.; Bolm, C. On the Role of Metal Contaminants in Catalyses with FeCl3 Angew. Chem. Int. Ed.  2009, 48, 5586-5587
321 Taylor, A.M.; Altman, R.A. and Buchwald, S.L. Palladium-catalyzed Enantioselective a-arylation and a-vinylation of Oxindoles. J. Am. Chem. Soc. 2009, 131, 9900–9901
320 Hyde, A. M.; Buchwald, S. L. Synthesis of 5,5-Disubstituted Butenolides Based on a g-Arylation Strategy. Org. Lett. 2009, 11, 2663-2666
319 Han, C. and Buchwald, S.L. Negishi Coupling of Secondary Alkylzinc Halides with Aryl Bromides and Chlorides. J. Am. Chem. Soc. 2009, 131, 7532-7533
318 Fors, B.P., Dooleweerdt, K., Zeng, Q. and Buchwald, S.L. An Efficient System for the Pd-catalyzed Cross-Coupling of Amides and Aryl Chlorides. Tetrahedron 2009, 65, 6576-6583
317 Garcia-Fortanet, J.; Kessler, F. and Buchwald, S.L. Palladium-Catalyzed Asymmetric Dearomatization of Naphthalene Derivatives. J. Am. Chem. Soc .2009, 131, 6676-6677
316 Fors, B.P.; Davis, N. and Buchwald, S.L. An Efficient Process for Pd-Catalyzed C–N Cross-Coupling Reactions of Aryl Iodides:  Insight Into Controlling Factors. J. Am. Chem. Soc. 2009,131, 5766-5768
315 Lee, B.K.; Biscoe, M.R. and  Buchwald, S.L. A Simple, Efficient Protocol for the Pd-Catalyzed Cross-Coupling Reaction of Aryl Chlorides and Dimethylamine. Tet. Lett. 2009, 50, 3672-3674
314 Biscoe, M.R. and  Buchwald, S.L. The Selective Monoarylation of Acetate Esters and Aryl Methyl Ketones Using Aryl Chlorides. Org. Lett. 2009, 11, 1173-1775
313 Strieter, E.R.; Bhayana, B. and Buchwald, S.L. Mechanistic Studies on the Copper-Catalyzed N-Arylation of Amides. J. Am. Chem. Soc. 2009, 131, 78-88

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