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2012

SLB # 1 Authors Title Journal Reference and DOI Link
  Milner, P. J., Maimone, T. J., Su, M., Chen, J., Müller, P., Buchwald, S. L. Investigating the Dearomative Rearrangement of Biaryl Phosphine-Ligated Pd(II) Complexes J. Am. Chem. Soc. 2012, 134, 19922-19934
  Yang, Y., Oldenhuis, N.J., Buchwald, S.L. Mild and General Conditions for Negishi Cross-Coupling Enabled by the Use of Palladacycle Precatalysts Angew. Chem. Int. Ed. 2012, 52, 615-619
  Spokoyny, A.M., Lewis C. D, Teverovskiy G., Buchwald, S. L. Extremely Electron-Rich, Boron-Functionalized, Icosahedral Carborane-Based Phosphinoboranes Organometallics 2012, 31, 8478-8481
  Ueda S., Buchwald, S.L. Catalyst-Contolled Chemoselective Arylation of 2-Aminobenzimidazoles
  Oberli, M.A., and Buchwald, S.L. A General Method for Suzuki-Miyaura Coupling Reactions using Lithium Triisopropyl Borates
  Chueng, C.W., and Buchwald, S.L. Room Temperature Copper(II)-Catalyzed Oxidative Cyclization of Enamides to 2,5-Disubstituted Oxazoles via Vinylic C-H Functionalization
  Pellegatti, L., and Buchwald, S.L. Continuous-Flow Preparation and Use of ß-Chloro Enals Using Vilsmeier Reagent Org. Process Res. Dev. 2012, 16, 1442-1448
  Zhu, R., and Buchwald, S.L. Copper-Catalyzed Oxytrifluoromethylation of Unactivated Alkenes J. Am. Chem. Soc. 2012, 134, 12462-12465
  Chernyak, N., and Buchwald, S.L. Continuous-Flow Synthesis of Monoarylated Acetaldehydes using Aryldiazonium Salts J. Am. Chem. Soc. 2012, 134, 12466-12469
  Hoshiya, N., and Buchwald, S.L. An Improved Synthesis of BrettPhos- and RockPhos-Type Biarylphosphine Ligands
  Vinogradova, E.V., Fors, B.P., and Buchwald, S.L. Palladium-Catalyzed Cross-Couping of Aryl Chlorides and Triflates with Sodium Cyanate: A Practical Synthesis of Unsymmetrical Ureas
  McGowan, M. A., McAvoy, C.Z., and Buchwald, S.L. Palladium-Catalyzed N-Monoarylation of Amidines and a One-Pot Synthesis of Quinazoline Derivatives
  Shu, W., and Buchwald, S.L. Enantioselective β-Arylation of Ketones Enabled by Lithiation/Borylation/1,4-Addition Sequence Under Flow Conditions Angew. Chem. Int. Ed. 2012, 51, 5355-5358
  Su, M., and Buchwald, S.L. A Bulky Biaryl Phosphine Ligand Allows for Palladium-Catalyzed Amidation of Five-Membered Heterocycles as Electrophiles Angew. Chem. Int. Ed. 2012, 51, 4710-4713
  McGowan, M.A., Henderson, J.L., and Buchwald, S .L. Palladium-Catalyzed N-Arylation of 2-Aminothiazoles Org. Lett. 2012, 14, 1432-1435
  Ueda, S., Ali, S., Fors, B.P., and Buchwald, S. L. Me3(OMe)tBuXPhos: A Surrogate Ligand for Me4tBuXPhos in Palladium-Catalyzed C–N and C–O Bond-Forming Reactions J. Org. Chem. 2012, 77, 2543-2547
  Parsons, A. T., Senecal, T. D., and Buchwald, S.L. Iron(II)-Catalyzed Trifluoromethylation of Potassium Vinyltrifluoroborates Angew. Chem. Int. Ed. 2012, 51, 2947-2950
  Zhu, R., and Buchwald, S.L. Combined Oxypalladation/C–H Functionalization: Palladium(II)-Catalyzed Intramolecular Oxidative Oxyarylation of Hydroxyalkenes Angew. Chem. Int. Ed. 2012, 51, 1926-1929
  Salvi, L., Davis, N.R., Ali, S. Z., and Buchwald, S.L. A New Biarylphosphine Ligand for the Pd-Catalyzed Synthesis of Diaryl Ethers under Mild Conditions Org. Lett. 2012, 14, 170-173
  Ueda, S., Su, M., and Buchwald, S.L. Completely N1-Selective Palladium-Catalyzed Arylation of Unsymmetric Imidazoles: Application to the Synthesis of Nilotinib J. Am. Chem. Soc. 2012, 134, 700-706

2011

SLB # 1 Authors Title Journal Reference and DOI Link
  Cho, E.J., and Buchwald, S.L. The Palladium-Catalyzed Trifluoromethylation of Vinyl Sulfonates Org. Lett. 2011, 13, 6552-6555
  Wang, X., and Buchwald, S.L. Rh-Catalyzed Asymmetric Hydroformylation of Functionalized 1,1-Disubstituted Olefins J. Am. Chem. Soc. 2011, 133, 19080-19083
  Maimone, T.J., Milner, P.J., Kinzel, T., Zhang, Y., Takase, M.K., and Buchwald, S.L. Evidence for in Situ Catalyst Modification during the Pd-Catalyzed Conversion of Aryl Triflates to Aryl Fluorides J. Am. Chem. Soc. 2011, 133, 18106-18109
  Shu, W., Pellegatti, L., Oberli, M.A., and Buchwald, S.L. Continuous-Flow Synthesis of Biaryls Enabled by Multistep Solid-Handling in a Lithiation/Borylation/Suzuki–Miyaura Cross-Coupling Sequence Angew. Chem. Int. Ed. 2011,50, 10665-10669
  Wu, X., Fors, B.P., and Buchwald, S.L. A Single Phosphine Ligand Allows Palladium-Catalyzed Intermolecular C–O Bond Formation with Secondary and Primary Alcohols Angew. Chem. Int. Ed. 2011, 50, 9943-9947
  Shu, W., and Buchwald, S.L. Use of Precatalysts Greatly Facilitate Palladium-Catalyzed Alkynylations in Batch and Continuous-Flow Conditions Chem. Sci. 2011, 2, 2321-2325
  Parsons, A.T., and Buchwald, S.L. Copper-Catalyzed Trifluoromethylation of Unactivated Olefins Angew. Chem. Int. Ed. 2011, 50, 9120-9123
  Pan, J., Wang, X., Zhang, Y., and Buchwald, S.L. An Improved Palladium-Catalyzed Conversion of Aryl and Vinyl Triflates to Bromides and Chlorides Org. Lett. 2011, 13, 4974-4976
  Tsvelikhovsky, D., and Buchwald, S.L. Concise Palladium-Catalyzed Synthesis of Dibenzodiazepines and Structural Analogues J. Am. Chem. Soc. 2011, 133, 14228-14231
  Ueda, S., Su, M., and Buchwald, S.L. Highly N2-Selective Palladium-Catalyzed Arylation of 1,2,3-Triazoles Angew. Chem. Int. Ed. 2011, 50, 8944-8947
  Noël, T., Maimone, T.J., and Buchwald, S.L. Accelerating Palladium-Catalyzed C-F Bond Formation: Use of a Microflow Packed-Bed Reactor Angew. Chem. Int. Ed. 2011, 50, 8900-8903
  Noël, T., and Buchwald, S.L. Cross-coupling in flow Chem. Soc. Rev. 2011, 40, 5010-5029
  Pan, J., Su, M., and Buchwald, S.L. Palladium(0)-Catalyzed Intermolecular Amination of Unactivated Csp3–H Bonds Angew. Chem. Int. Ed. 2011, 50, 8647-8651

  Teverovskiy, G., Surry, D.S., and Buchwald, S.L. Pd-Catalyzed Synthesis of ArSCF3 Compounds under Mild Conditions Angew. Chem. Int. Ed. 2011, 50, 7312-7314
  Li, P., and Buchwald, S.L. Continuous-Flow Synthesis of 3,3-Disubstituted Oxindoles by a Palladium-Catalyzed α-Arylation/Alkylation Sequence Angew. Chem. Int. Ed. 2011, 50, 6396-6400
  Rousseaux, S., Garcia-Fortanet, J., Del Aguila Sanchez, M.A., and Buchwald, S.L. Palladium(0)-Catalyzed Arylative Dearomatization of Phenols J. Am. Chem. Soc. 2011, 113, 9282-9285
link Breitler, S., Oldenhuis, N.J., Fors, B.P., and Buchwald, S.L. Synthesis of Unsymmetrical Diarylureas via Pd-Catalyzed C–N Cross-Coupling Reaction Org. Lett. 2011, 13, 3262-3265
  Noël, T., Kuhn, S., Musacchio, A.J., Jensen, K.F., and Buchwald, S.L. Suzuki–Miyaura Cross-Coupling Reactions in Flow: Multistep Synthesis Enabled by a Microfluidic Extraction Angew. Chem. Int. Ed. 2011, 50, 5943-5946
  Senecal, T.D., Parsons, A.T., and Buchwald, S.L. Room Temperature Aryl Trifluoromethylation via Copper-Mediated Oxidative Cross-Coupling J. Org. Chem. 2011, 76, 1174-1176
349 Noël, T., Naber, J.R., Hartman, R.L., McMullen, J.P., Jensen, K.F., and Buchwald, S.L. Palladium-Catalyzed Amination Reactions In Flow: Overcoming the Challenges of Clogging Via Acoustic Irradiation Chem. Sci. 2011, 2, 287-290
340 Surry, D.S., and Buchwald, S.L. Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide Chem. Sci. 2011, 2, 27-50
339 Maiti, D., Fors., B.P., Henderson, J.L., and Buchwald, S.L. Palladium-Catalyzed Coupling of Functionalized Primary and Secondary Amines With Aryl and Heteroaryl Halides: Two Ligands Suffice in Most Cases Chem. Sci. 2011, 2, 57-68

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