No Navigation In This Section

IRG-III Highlights

IRG-III researchers demonstrate nanoscale cation motion in memristive systems

Scanning tunnelling switching at positive tip voltages. a, I–t dependence measured on a TaOx layer showing no quantum point contact after the voltage is decreased. The initial current increase is related to a different switching mechanism, possibly predominantly involving the diffusion of oxygen vacancies. b, Surface image of the TaOx layer recorded directly after time-resolved STM measurements at positive tip voltages applying a scanning bias voltage of 1 V to the STM tip and with a tunnelling current setpoint of 1 nA. Diffuse conductive regions are visible at the positions where local resistive switching was performed. Current–voltage curves measured on these regions show semiconducting behaviour.

A detailed understanding of the resistive switching mechanisms that operate in redox-based resistive random-access memories (ReRAM) is key to controlling these memristive devices and formulating appropriate design rules. Based on distinct fundamental switching mechanisms, two types of ReRAM have emerged: electrochemical metallization memories, in which the mobile species is thought to be metal cations, and valence change memories, in which the mobile species is thought to be oxygen anions (or positively charged oxygen vacancies). Here we show, using scanning tunnelling microscopy and supported by potentiodynamic current–voltage measurements, that in three typical valence change memory materials (TaOx, HfOxand TiOx) the host metal cations are mobile in films of 2 nm thickness. The cations can form metallic filaments and participate in the resistive switching process, illustrating that there is a bridge between the electrochemical metallization mechanism and the valence change mechanism. Reset/Set operations are, we suggest, driven by oxidation (passivation) and reduction reactions. For the Ta/Ta2O5 system, a rutile-type TaO2 film is believed to mediate switching, and we show that devices can be switched from a valence change mode to an electrochemical metallization mode by introducing an intermediate layer of amorphous carbon.

Anja Wedig, Michael Luebben, Deok-Yong Cho, Marco Moors, Katharina Skaja, Vikas Rana, Tsuyoshi Hasegawa, Kiran K. Adepalli, Bilge Yildiz, Rainer Waser, and Ilia Valov

Read the full article here.

 

Highlights Main Index

CMSE Home

Research

Educational Outreach

Facilities

Connecting to Industry

Highlights

News and Publications

People

About CMSE

Related Links

BUILDING INFO & SAFETY | CONTACT US | SEARCH | MATERIALS CALENDAR
CMSE Nuggets