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I joined MIT as a postdoctoral associate in 2006, after finishing my Ph.D. with Prof. T. Sridhar at Monash University, Australia. During my Ph.D. work, I studied the extensional flow behavior of polymer solutions using the filament stretching extensional rheometric technique. At MIT, I work at the Institute for Soldier Nanotechnologies, under the combined supervision of Prof. G. H. McKinley (Mechanical Engineering), and Prof. G. C. Rutledge (Chemical Engineering). The major focus of my research at MIT-ISN is to understand the role that the fluid viscoelasticity plays in manufacturing polymer fibers using the electrospinning process. A brief description of the projects I am invovled in is provided below.
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Electro-spinning
is a process of manufacturing fine fibers from polymeric fluids using an
electric field. Recent interest in electro-spinning arises from its potential
use in the fabrication of nano-fibers for various applications. In
a typical electro-spinning process the polymeric fluid undergoes substantial
deformation at very large deformation rates. This invokes a characteristic
viscoelastic response from the fluid which critically influences, both
the stability of the process, as well as the final characteristics of the
product fiber. In the current research project these effects are systematically
being studied. Particular emphasis is being directed towards the understanding
of how the fluid properties affect the diameter of the product fibers.
The goals of this project are as follows.
The
dynamics of polymer molecules in extensional flows is interesting since
such flows arise in a number of important polymer processing operations
like melt spinning, film blowing, injection molding etc. The above mentioned
electro-spinning process also uses a predominantly extensional mode of
deformation. These processes typically elongate the polymeric fluids by
large amounts, leading to substantial orientation, and stretching, of the
polymer chains. The resulting stress in the fluid gives rise to spectacular
non-Newtonian effects which play a critical role in determining the stability
of the process. These non-linear effects in extensional flow can now be
studied using the Filament Stretching Extensional Rheometer (FiSER), from
a fundamental stand-point. Current topics of interest include characterization
of extensional flow behavior in polymer melts.
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