Bi- and trilayer graphene solutions

Research areas:
  • Uncategorized
Year: 2011
Type of Publication: Article
Authors:
  • Chih-Jen Shih, Rajasekar Krishnan Aravind Vijayaraghavan
Journal: Nature Nanotechnology Volume: 6
Number: 7 Pages: 439-445
Month: JUL 2011
Note:
PT: J; TC: 2; UT: WOS:000292463000014
Abstract:
Bilayer and trilayer graphene with controlled stacking is emerging as one of the most promising candidates for post-silicon nanoelectronics. However, it is not yet possible to produce large quantities of bilayer or trilayer graphene with controlled stacking, as is required for many applications. Here, we demonstrate a solution-phase technique for the production of large-area, bilayer or trilayer graphene from graphite, with controlled stacking. The ionic compounds iodine chloride (ICl) or iodine bromide (IBr) intercalate the graphite starting material at every second or third layer, creating second-or third-stage controlled graphite intercolation compounds, respectively. The resulting solution dispersions are specifically enriched with bilayer or trilayer graphene, respectively. Because the process requires only mild sonication, it produces graphene flakes with areas as large as 50 mu m(2). Moreover, the electronic properties of the flakes are superior to those achieved with other solution-based methods; for example, unannealed samples have resistivities as low as similar to 1 k Omega and hole mobilities as high as similar to 400 cm(2) V(-1) s(-1). The solution-based process is expected to allow high-throughput production, functionalization, and the transfer of samples to arbitrary substrates.