WPC2$ ԂH;p7L5nL =+׸QDЉzg3z`4PZBb ^ IWwQknfpNͼ 8cF*ֺƅ֢}7*2tJy.8fFF$=)|%'_ o@GYQ|#L]+~$3pc829"܃ߡ'w[ NxSJ4ʁs!ρ'&IiǺNf0zշ ==g;_udT] AG))8SfHUΙ!5;<2>,p }|>6ܣb Cq/IB4Wr"IzQz֢^뚅HB;rc-==NGA&WCaɫ_(2ITiޛl# UDN %A 0(G U<o UN w@ 49 M U<\ UN U< UN" U<p UN U< UN6 U< UN U< UNJ U< U< UNU<^UNU<UN$U<rUNU<UN8UN~U<RUNU<UNU<fU NU<U N,U<zUNU<UN@UNU<U NU<f 0NUNU<>UNzU<UNU<RUNU<UNU<f BU<UNU<IUNU<UNUN]U<UN5 m7UNNUNU<UN& 0@tU<EU<U<.UNjUNU<UNBU<UN"U:<UNvU<UN U<N UN U< UN!UNb!U<!UN!UL:"UN"U<"UL#U<\#UL#UN#HP DeskJet 540 PrinterDESKJETC,hh,0(9 Z 6Times New Roman RegularX($:   Z$Symbol Regular(9 Z 6Times New Roman Regular y z { | } ~ {  E  P2""|x :   Z$Symbol Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular(9 Z 6Times New Roman Regular 1stdWdx EqsWsEqLegendrerxmembered:   Z$Symbol Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular>$"Small Circle"0  (9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular d:   Z$Symbol Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman RegularU(9 Z 6Times New Roman Regular(9 Z 6Times New Roman Regular9:  Z$Symbol Regular(9 Z 6Times New Roman Regular2c0Quick 220 :   Z$Symbol Regular:   Z$Symbol Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular  H X ,rAZ"Arial Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular(9 Z 6Times New Roman Regular:   Z$Symbol Regular(9 Z 6Times New Roman Regular4 4Bookman Old Style Bold(9 Z 6Times New Roman Regular:   Z$Symbol Regular4 4Bookman Old Style Bold:   Z$Symbol Regular4 4Bookman Old Style Bold(9 Z 6Times New Roman Regular !  HH*,XX XX* YsCErrataforthe1stPrintingofthe3rdeditionofThermodynamicsandItsApplications H М Author'snote:Allofthesecorrectionswillappearinthe2ndandsubsequentprintingsofthe3rdedition.Theprintingordercanbeidentifiedbythelowestnumberinasequenceofnumbers10...to...1,foundjustabovetheISBNnumberonthecopyrightpage(iv)whichisthepagerightbeforetheTableofContents.̜ PartI   t Є  pxiii,2ndparagraph,line16,"efforts"shouldbe"effects"  ` Є  p30,line14change z to x inX‘XXXԢdX5 XXX‘W= F  d x   L  Є  p38,Figure3.8,P1>P2>P3shouldbeX5 XXX5 Ԁ#X5 XXX5 #X5 XXX5 ԀP3>P2>P1#X5 XXX5 #  D  Є  p84,Example4.3,insert(W)after"network"thefirsttimeitappearsonline9inthe x 0    Solutionpart d  0     p95,line3,insert"element9XXXX5 d:X5 XX9Xn"after..."fluid"...;andinline2ofthenexttothelastP (#(# Ѐparagraph,insert"(i.e.thecompressororturbine)"after..."engine"...̄0  p97,Example4.6,line3andbelow,"donebythecompressoronthegas"...andinEqs.4 (#(# Ѐ(479),(482),and(483)changesignsto+signs.InEqs.(479),(480)and(482),     change򛀢WXP XX:X5 s!X5 X XXPԀtoWsandinEq.(480)invertthetermsinthelnargumenttoln(Pa/Pt)   Є0  p151,Table5.2,thefunctionandcanonicalcoordinatesentriesforenthalpyneedtobe(#(# Ѐcorrectedtoready(1)andS,P,Ni(i=1,...,n),respectively.    p179,nexttothelastline,QXG XX!X5 dSX5 X XQXGzinotX‘XXSX5 d#SX5 XXX‘* #X5 XXSX5 z1#SX5 XXX5 m #  Є  p182,Eq.(612),inthedoublesummation,^XYy XXSX5 d_X5 X X^XYy2Ushouldbe,X5 Xh_X5 2U#_X5 XXX5 u #  Є  p187,Table6.1,subscriptscontainingTandPshouldbeTandPwithoutunderbars. x  PartII  P М  p274,2ndparagraph,2ndline,"could"ratherthan"would" < Є  p286,Eq.(8161)shouldread?Xx XX_X5 Ԣg@X5 X X?XxG=AXXX@X5 aBX5 XXAXpV/(CXDXXBX5 ԢkDX5 XXCXDTCv)andinthelastlinebeforesection8.7,FXAXXDX5  p( Ѐ0  eGX5 XXFXAxEX5 XXGX5 =0.076(or7.6%)notX5 XXEX5 Ԁ#EX5 XXX5 #X‘XXEX5 Ԣe#EX5 XXX‘@#X5 XXEX5 xo#EX5 XXX5 #Ԁ=0.086(8.6%).h (#(# Є  p305,FigureP8.16,delete"Nitrogen"fromthelabelonthesupplymanifold. ` Є  p313,Problem8.25,line10, statenot sate. L Є  p318,lastline,andp319,line3,i=1,...nnoti=1,...N. 8 Є  p326,thirdequation,signafter1stterminlargebracketsshouldbe+ $  Є  p343,onelinebelowEq.(998),seeSection9.5not9.6 !  М  p351,2linesaboveEq.(9145),referencetoEq.(995)shouldbeEq.(992) !! Є  p358,Figure9.3,invertthe5XXXEX5 Ԣg6X5 XX5X1and7XpXX6X5 Ԣg8X5 XX7Xp2labelsonthelefthandgraphalsotherighthand ""   sidederivativeintheequationatthetopofthatgraphshouldread,lnX‘XX8X5 Ԣg#8X5 XXX‘#X5 XX8X5 1#8X5 XXX5 @#/X5 XX8X5 ,#8X5 XXX5 #x1 # # М  p360,2ndparagraph,line4,Section13.4ratherthanSection11.5. $!$ Є  p363,6linesfrombottom,infinitelynotinifinitely %|"% X5 XX8X5 0     p367,Eq.(9208)andworktermsinExample9.8belowshouldallbepositive,e.g. &h#& +YXX5 (#X5 XYd#VdP=+RT#8X5 XXX5 #X5 XX8X5 YXX5 (#X5 XY#dlnP#8X5 XXX5 #X5 XX8X5 Ԁ=+(8.314)(300)ln(1/0.8)=+557J/molN2,etc.'T$'(#(# #8X5 XXX5 #Ԅ  p368,line5,change)X.XX8X5 ԢD*X5 XX)X.GnettoX5 XX*X5 #*X5 XXX5 #X‘XX*X5 ԢD#*X5 XXX‘#X5 XX*X5 Gmix#*X5 XXX5 0# (h%( Є  p381,1stand2ndlinesofTable,..."cyclohexaneinmethylethylketone"... )`&) Є  p400,2linesaboveEq.(1044),k=1.38048'1023minussignmissingintheexponent *L'* М  p429,4linesafterEq.(10147),"accessible"not"accessbile"and2linesabove +8(+   Eq.(10146),linearlyratherthanlinearilȳ  p434,equationaboveEq.(10156),U=Uidealgas+<U>notX5 XX*X5 ԀU=#*X5 XXX5 #X5 XX*X5 Uidealgas=<U>#*X5 XXX5 # X-*- X5 XX*X5 Ԅ  p437,Table10.4,lasttermintheReeHooverexactexpansionshouldbe56.7y6#*X5 XXX5 #X5 XX*X5   D.*.  0/+/ YsCHHXH  Part #*X5 XXX5 ?#X5 XX*X5 Ԁ IIcont #*X5 XXX5 # X ̣  p439,equationinExample10.1,iX>XX*X5 tkX5 XXiX>inthelargebracketsshouldbeM 4 Є  p444,lastlineoftext,Eq.(1078)notEq.(10178) , Є  p459,Eq.(117),lnRXvXXkX5 gTX5 XhRXvishouldbelnUXpXXTX5 gVX5 XXUXp1  Є  p467,Eq.(1134),+ratherthankTNA(...)  Є  p471,Eq.(1149),<WXP XXVX5 FXX5 X XWXPij>/kT,minussignmissing  Є  p490,7thlineoftextbelowEq.(1188),insert"(seeSection13.4)"after"...method."  Л0     p507,relabelEq.(129)as(12.9a)in2places,andchangelabelforEq.(1213)to (#(#    ` Eq.(129b)̄  p508,Eq.(1212b)shouldread  `     `     h   m =XYXXX5 Ԁ[#XX5 XXY##Ԁ( m i)=X!XhXX5 ni( KX5 X!X=Xm j)OXe%XhKX5 ԢnMX5 X%hOXej]1/LX'XhMX5 nJX5 X'XLX  L  Є  p513,changeEq.(1227)andthelinebelowittoread:     x   `     `     X)XXJX5 Ԣd X5 X)X XWrev= X*XX X5 $ X5 X*X XԢdq=X,XX X5 $X5 X,XX(X'-XXX5  .-XX'S#X'-X. 4&#ԀnX5 X-hX'izi)FdX0XXX5 xX5 X0XX=neFX2XXX5 $X5 X2XXdX!4XXX5 x   x X5 X4XX!(1227) L     ` wherene=netmolesofelectronstransferredinthereactionpermoleofreactant, h     ` Xn5XXX5 xX5 X5XXnԀ=theextentofreaction[seeEq.(651)]andF=Faraday'sconstant... T Є  p513,deletethetwolinesoftextbelowthedefiningequationforX6XXX5 $X5 X6XXX*7XXX5 ԢyX5 X7XX*2󀄀Xh8XXX5 Ԣy X5 X8XXh1 L М  p513,replacethelastfourlinesonthepagethatincludestheequationwith: D 0  0` (#(#...LegendretransformwithrespecttoSTandVX5 XX X5 P# X5 XXX5 7+#Ԁconjugatevariablechanges, 0 weobtainthetotalGibbsfreeenergyGindifferentialformwithPdVandX‘XX X5 $# X5 XXX‘,#dq t workeffectsincludedas ` (#` (#    ` dG=SdT+VdP+ YX X5 # X5 X Y,#'X;XX X5 m(X5 X;X'XidNi+X5 XX(X5 neF#(X5 XXX5 -#X‘XX(X5 $#(X5 XXX‘-#X5 XX(X5 d#(X5 XXX5 9.#X‘XX(X5 x=#(X5 XXX‘.#X5 XX(X5 SdT+VdP#(X5 XXX5 .#X‘XX(X5 Ԁ+(#(X5 XXX‘0/#X5 XX(X5 YXX5 #(YYv/##(X5 X(Y/#+X<XX(X5 Ԣn,X5 X<X+Xi-X=XX,X5 m.X5 X=X-XiX5 XX.X5 +#.X5 XXX5 0#X5 XX.X5 neF#.X5 XXX5 0#X‘XX.X5 $)#.X5 XXX‘/1#X5 XX.X5 d#.X5 XXX5 v1#X‘XX.X5 x#.X5 XXX‘1#X‘XX.X5  X #.X5 XXX‘2#/X5 XX.X5 0  0` (#(#whichcanbeintegratedfromX‘XX/X5 x#/X5 XXX‘2#Ԁ=0to1,notingthatX5 XX/X5 dG#/X5 XXX5 3#Ԁ=0forasystemat l equilibrium  d ` (#` (# Є0  X5 XX/X5 p514,insertsubscriptrxonall#/X5 XXX5 3##X>XX/X5 D$X5 X>X#XGterms,e.g.%X?XX$X5 ԢD&X5 X?X%XGrx,andreplacethetop3linesthat P includesEq.(1228)with: (#(# 0  0` (#(#...atconstantT,P,andtotalmass.Thus,foranisobaric,isothermal,fully 4 reversibleelectrochemicalcell: ` (#` (#    `     h   0XG@XX&X5 ԢD1X5 X@X0XGGrx=X5 XX1X5  6A XX5 #X5 XA  66##1X5 XXX5 6#X‘XX1X5 Ԣn#1X5 XXX‘/7#X5 XX1X5 i#1X5 XXX5 s7#X‘XX1X5 m#1X5 XXX‘7#X5 XX1X5 i#1X5 XXX5 8#Ԁ=X5 XX1X5 Ԁ#1X5 XXX5 ]8#X5 XX1X5 neF#1X5 XXX5 8#X‘XX1X5 $#1X5 XXX‘8#Ԁ   x (1228)   ̄  p514,replaceEq.(655)atthebottomofthepageandthe4linesaboveitwith: 0    ` ...anyrealconditionto2XCXX1X5 ԀX‘XCX2XԢD#2XCXXX‘2:#X5 XCX2XGrx#2XCXXX5 v:#]4X5 XCX2Xatstandardstateconditionsusingamodifiedform      ` ofthecriteriaofEq.(655)forareversiblechemicalreactionatequilibrium.The   ` modifiedcriteriaisactuallygivenaboveinEq.(1228)whichinthepresenceofan   ` finiteelectricpotentialX‘XX4X5 $#4X5 XXX‘G<#Ԁisnotequaltozero. " " 0     p515,line1,insertsubscriptrxonX‘XX4X5 D#4X5 XXX‘ =#X5 XX4X5 Gand#4X5 XXX5 O=#X‘XX4X5 ԢD#4X5 XXX‘=#X5 XX4X5 Goterms;andonelinebelowEq(1231), #!#  ` changethereferencetoEq.(1213)toEq.(129b) (#(# #4X5 XXX5 =#Ԅ  p519,equationbelowEq.(1238),ziintheexponenttermshouldbezj %p#% Є  p528,Section12.5,2ndparagraph,line2,X5 XX4X5 ԢRasaiah#4X5 XXX5 ?#ԀnotRassiah &\$& Є  p535,3rdparagraph,3rdline,ZernikenotZernicke 'H%' Є  p545,Example12.4,theentryfor;X̛GXX4X5 r<X5 XGX;X̛Ԁof1.798shouldbe1.130 (4&( Є  p546,Figure12.10,lowerlineinbothgraphsshouldbe& &(DebyeHuckel)andtheline ),')    ` justaboveitshouldbe(PitzerextendedDH)̄  p548,under(1), m HCl=4.5/(1.12.001((4.5)(36.5)+(1.33)(58.5)))=5.126mol/kg \+)+    ` andonelineabovethefigurechange1.33to1.5̜ /,/ Ї PartIIcont.  X Є  p558,Figure13.1,underFunctionalgroupscolumn, D    `  2:>CHX5 XX<X5 #<X5 XXX5 XC#Ԁ(ring)inplaceof1:X5 XX<X5 >CH#<X5 XXX5 C#Ԁ(ring) 0    `  2:X5 XX<X5 #<X5 XXX5 @D#ԢCH2X5 XX<X5 #<X5 XXX5 D#Ԁ(ring)inplaceof1:X5 XX<X5 Ԁ#<X5 XXX5 D#X5 XX<X5 #<X5 XXX5 0E#X5 XX<X5 ԢCH2#<X5 XXX5 vE#X5 XX<X5 #<X5 XXX5 E#X5 XX<X5 Ԁ(ring)#<X5 XXX5 F#     `  1:X5 XX<X5 #<X5 XXX5 F#N=(ring)inplaceof2:X5 XX<X5 #<X5 XXX5 F#X5 XX<X5 N=(ring)#<X5 XXX5 3G#     `  1:>NH(ring)inplaceof2:X5 XX<X5 Ԁ>NH(ring)#<X5 XXX5 G#  0  0` (#(#Inaddition,thestructuralformulaforAlphaxyzismissingaNatomatthe"6o'clock"positionofthesixmemberedring. ` (#` (# ̜ PartIII   L  М  p594,line4,`X-HXX<X5 haX5 XHX`X-Carnot=(THTC)/TH  8  Є  p595,2ndparagraph,line4,changeEq.(1427)to(1426)  0  Є  p603,Eq.(1445),missingsubscript"in"onT,shouldbeTin t   Є  p610,line5,TAandpointAshouldbeX5 XXaX5 TBandpointB#aX5 XXX5 J# `  Є  p617,Figure14.14(b),thestatepointattheintakeandexhaustconditionshouldbe L     ` Dnot B. 8  Є  p618,Eq.(1462),VDshouldbeVB $ Є  p624,FigureP14.4,addtocaption,(notethatnsisbasedonrotationalspeedinradians    persecondratherthanrevolutionspersecond)̄  p681,1linebelowEq.(1561),Eq.(8121)andEq.(8123)shouldbe(9112)and(9114)  Є  p682,2linesaboveEq.(1567),"...thenumeratoris..." | Є  p686687,Example15.5,inthefirst4equationsofthesolution,thefirstequalsign(=) h   shouldbeaminussign() T Є  p689,3rdline,referencetoTables8.1and9.2shouldbetoTables8.1and8.2 @ Є  p692,{ one{ linebelowEq.(15z 95z y 37y ),referenceshouldbetoEq.(1595) , Є  p699,3rdparagraph,1stline,Figure9.8not9.7 p Є  p704,3linesfrombottom,referencetoExample15.7shouldbeto15.8 \ Є  p708,Example15.7shouldbe15.8 H Є  p733,Problem15.22,2ndparagraph,Figure15.29not8.2 4   p742,line2,,\Xk=IXXaX5 c]X5 XIX\Xk=ishouldbe,xiandonFigureP15.33(b),xaxislabelshouldber1/2+(2r)1     andyaxislabelshouldbe(K1)  Є  p743,part(b),referencetoFigureP15.36shouldbeFigure15.22  Є  p744,Problem15.37,5thline,minussignmissingin(<50$C)   Є  p763,lineaboveEq.(1630),seeSection9.7not8.5  ! X5 XX]X5 Ԅ  p786,equationaboveEq.(1680)summationshouldrunoverjci#]X5 XXX5 S# !p" Є  p828,1linebelowEq.(1711),insert"whereCjisequivalenttotheformulavectorWj "\ #   giveninEq.(1611)." #H!$ Є  p837,Eq.(1744),nncXJXh]X5 (p)fX5 XJXcXԀshouldbeX5 XXfX5 xn#fX5 XhX5 U#X‘XhfX5 (p)#fX5 XXX‘V#X5 XXfX5 Ԁ#fX5 XXX5 cV# $4"% Є  p852,Problem17.3,part(a),5thline,Equation(1)shouldbeEq.(1754) x% #& Є  p856857,Problem17.9,allreferencestoFigureP17.10shouldbetoP17.9 d& $' Є  p869,Example18.6,lastequation,P(V)(jXF"MXXfX5 HBbX5 XMXjXF")(V)=X5 XXbX5 P(L)#bX5 XXX5 FX#X5 XXbX5 (#bX5 XXX5 X#eXF"MXXbX5 HB#bX5 XMXeXF"X#X5 XXbX5 )(L)#bX5 XhX5 *Y#X5 XhbX5  P'$(   p870,3rdequation,#bX5 XXX5 yY# B ext=gXyNXXbX5 mM$hXF"MXNXgXyHdX5 XMXhXF"ext <(%) IfyoufindanymoreerrorsinthefirstprintingpleaseforwardthemtoProf.JeffTester  *'+ ЀatZX,JRXXdX5 Ԁ[X5 XRXZX,Jthermocom@mit.edu.Thanks.  +(, A>P) xdE-xAߛ -|+/  X5 XX[X5 ؓTXX5 Prof.JeffTester0 ` 0 ` (#` (#0 (# (#0h(#(#  0h(#h(# p ChemicalEngineeringDepartmentand-+0(#(# Мthermocom@mit.edu    h      p EnergyLaboratory,MIT .O,1 М~ } April} ~ ~ April~ } }  11   2 | January11| ,1997 `     h   0    p  Cambridge,MA02139 #[ؓTTؓ[##[X5 XT[ؓ\#