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Synthesis and Chemistry of Cyclopropylboranes

We have developed an efficient method for the synthesis of cyclopropylboranes from readily available dihalocyclopropanes.

References:

"Applications of Cyclopropylboranes in Organic Synthesis I. A Stereocontrolled Route to Substituted Cyclopropanol Derivatives", R. L. Danheiser and A. C. Savoca, J. Org. Chem. 1985, 50, 2401.

[ Home ] [ [2 + 2 + 2] Cycloaddition Strategies ] [ [3 + 2] Annulations of Organosilanes ] [ Vinylcyclopropane Rearrangements ] [ Cycloadditions and Annulations of Vinylketenes ] [ Highly Unsaturated, Conjugated Molecules ] [ [4 + 2] Cycloadditions of Imine Derivatives ] [ Ketene [2 + 2] Cycloadditions ] [ Acylsilanes ] [ B-Lactones ] [ Cyclopropylboranes ] [ Allenylsilanes and Homopropargylic Alcohols ] [ Cationic Cyclizations ] [ Synthesis of Azulenes ] [ Miscellaneous Synthetic Methods ]