The Role of Surface Oxidation in the Break-Up of Laminar Liquid Metal Jets
by
Pyongwon Yim
B.S. in Mechanical Engineering
Northeastern University
1987
M.S. in Mechanical Engineering
Northeastern University
1989
Submitted to the Department of Mechanical Engineering in Partial Fulfillment
of\ the Requirements for the Degree of
DOCTOR OF PHILOSOPHY IN MECHANICAL ENGINEERING
at the
MASSACHUSETTS INSTITUTE OF TECHNOLOGY
June 1996
ABSTRACT
The Uniform Droplet Spray (UDS) process, developed in the Laboratory for
Manufacturing and Productivity at MIT, offers many advantages over such
conventional metal droplet production processes as gas atomization. The
process exploits the acoustically-amplified capillary instability phenomenon
of laminar liquid jets to produce uniform liquid droplets, which allows
for greater control of the thermal state and mass flux of the droplet spray.
The present work investigates the varios basic phenomena associated with
teh UDS process. The thesis comprises three primary parts. The first part
investigates the break-up behavior of molten metal jets and compares the
results to theories by Lord Raleigh and others. This was achieved by spraying
pure tin into a chamber containing less than 5 ppm of oxtgen. The second
part investigaes the viability of the UDS process for producing large solder
balls that can be used for Ball-Grid Array (BGA) Integrated Circuit packaging.
it also examines whether the balls so produced are comparable to or better
than those produced by conventional processes. The final part investigates
the role of surface oxidation in the break-up behavior of liquid metal
jets. Again, pure tin was used in this part of the investigation to study
the effect of surface oxidation on jet break-up.
From the experimental results and theoretical considerations it is shown
that: (i) the break-up behavior of a molten metal jet can be explained
by Rayleigh's theory, provided that there is sufficiently low oxygen environment,
(ii) large solder calls can be produced cost effectively by the UDS process
for BGA packaging, and they are comparable to or better than those that
are produced by conventional processes in terms of dimensional tolerance
and microstructure, and (iii) the jet of molten tin does not break into
a train of uniform droplets if the spray chamber contains more than 1500
ppm of oxygen. Implications of these results to the desin and control of
the UDS process are discussed and research topics for further investigation
are suggested.

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