1. Spinney, H. A.; Piro, N. A.; Cummins, C. C., Triple-bond reactivity of an AsP complex intermediate: synthesis stemming from molecular arsenic, As4. J. Am. Chem. Soc. 2009, 131, 16233–16243.
  2. Cossairt, B. M.; Cummins, C. C., Properties and reactivity patterns of AsP3: an experimental and computational study of group 15 elemental molecules. J. Am. Chem. Soc. 2009, 131, 15501–15511.
  3. Curley, J. J.; Piro, N. A.; Cummins, C. C., A terminal molybdenum arsenide complex synthesized from yellow arsenic. Inorg. Chem. 2009, 48, 9599–9601.
  4. Cossairt, B. M.; Diawara, M.-C.; Cummins, C. C., Facile synthesis of AsP3. Science 2009, 323, 602–602.
  5. Curley, J. J.; Murahashi, T.; Cummins, C. C., Synthesis and reversible reductive coupling of cationic, dinitrogen-derived diazoalkane complexes. Inorg. Chem. 2009, 48, 7181–7193.
  6. Fox, A. R.; Cummins, C. C., Uranium-nitrogen multiple bonding: The case of a four-coordinate uranium(VI) nitridoborate complex. J. Am. Chem. Soc. 2009, 131, 5716–5717.
  7. Piro, N. A.; Cummins, C. C., An unusual P—P double bond formed via phospha-Wittig transformation of a terminal PO complex. J. Am. Chem. Soc. 2009, 131, 8764–8765.
  8. Piro, N. A.; Cummins, C. C., Tetraphosphabenzenes obtained via a triphosphacyclobutadiene intermediate. Angew. Chem. Int. Ed. 2009, 48, 934–938.
  9. Silvia, J. S.; Cummins, C. C., Two-electron reduction of a vanadium(V) nitride by CO to release cyanate and open a coordination site. J. Am. Chem. Soc. 2009, 131, 446–447.
  10. Betley, T. A.; Surendranath, Y.; Childress, M. V.; Alliger, G. E.; Fu, R.; Cummins, C. C.; Nocera, D. G., A ligand field chemistry of oxygen generation by the oxygen-evolving complex and synthetic active sites. Philos. Trans. R. Soc., B 2008, 363, 1293–1303.
  11. Christian, G.; Stranger, R.; Yates, B. F.; Cummins, C. C., Investigating CN– cleavage by three-coordinate M[N(R)Ar]3 complexes. Dalton Trans. 2008, 338–344.
  12. Clough, C. R.; Müller, P.; Cummins, C. C., 6-Coordinate tungsten(VI) tris-N-isopropylanilide complexes: Products of terminal oxo and nitrido transformations effected by main group electrophiles. Dalton Trans. 2008, 4458–4463.
  13. Cossairt, B. M.; Cummins, C. C., A niobium-mediated cycle producing phosphorus-rich organic molecules from white phosphorus (P4) through activation, functionalization, and transfer reactions. Angew. Chem. Int. Ed. 2008, 47, 8863–8866.
  14. Cossairt, B. M.; Cummins, C. C., Phosphaalkenes as long-lived phosphorus cluster surface functional groups: Intramolecular P=C addition to a niobium-supported P7 cage. Inorg. Chem. 2008, 47, 9363–9371.
  15. Cossairt, B. M.; Cummins, C. C., A reactive niobium phosphinidene P8 cluster obtained by reductive coupling of white phosphorus. Angew. Chem. Int. Ed. 2008, 47, 169–172.
  16. Curley, J. J.; Cook, T. R.; Reece, S. Y.; Müller, P.; Cummins, C. C., Shining light on dinitrogen cleavage: Structural features, redox chemistry, and photochemistry of the key intermediate bridging dinitrogen complex. J. Am. Chem. Soc. 2008, 130, 9394–9405.
  17. Fox, A. R.; Bart, S. C.; Meyer, K.; Cummins, C. C., Towards uranium catalysts. Nature 2008, 455, 341–349.
  18. McDonough, J. E.; Mendiratta, A.; Curley, J. J.; Fortman, G. C.; Fantasia, S.; Cummins, C. C.; Rybak-Akimova, E. V.; Nolan, S. P.; Hoff, C. D., Thermodynamic, kinetic, and computational study of heavier chalcogen (S, Se, and Te) terminal multiple bonds to molybdenum, carbon, and phosphorus. Inorg. Chem. 2008, 47, 2133–2141.
  19. Piro, N. A.; Cummins, C. C., P2 addition to terminal phosphide M—P triple bonds: A rational synthesis of cyclo-P3 complexes. J. Am. Chem. Soc. 2008, 130, 9524–9535.
  20. Temprado, M.; McDonough, J. E.; Mendiratta, A.; Tsai, Y.-C.; Fortman, G. C.; Cummins, C. C.; Rybak-Akimova, E. V.; Hoff, C. D., Thermodynamic and kinetic studies of H atom transfer from HMo(CO)3(η5-C5H5) to Mo(N[t-Bu]Ar)3 and (PhCN)Mo(N[t-Bu]Ar)3: Direct insertion of benzonitrile into the Mo−H bond of HMo(N[t-Bu]Ar)3 forming (Ph(H)CN)Mo(N[t-Bu]Ar)3. Inorg. Chem. 2008, 47, 9380-9389.
  21. Tonzetich, Z. J.; Schrock, R. R.; Wampler, K. M.; Bailey, B. C.; Cummins, C. C.; Müller, P., A tungsten(VI) nitride having a W2(μ-N)2 core. Inorg. Chem. 2008, 47, 1560-1567.
  22. Agarwal, P.; Piro, N. A.; Meyer, K.; Müller, P.; Cummins, C. C., An isolable and monomeric phosphorus radical that is resonance-stabilized by the vanadium(IV/V) redox couple. Angew. Chem. Int. Ed. 2007, 46, 3111-3114.
  23. Christian, G.; Stranger, R.; Yates, B. F.; Cummins, C. C., Cleavage of CO by Mo[N(R)Ar]3 complexes. Eur. J. Inorg. Chem. 2007, 2007, 3736-3741.
  24. Christian, G.; Stranger, R.; Petrie, S.; Yates, B. F.; Cummins, C. C., Breaking chemistry's strongest bond: Can three-coordinate [M{N(R)Ar}3] complexes cleave carbon monoxide? Chem. Eur. J. 2007, 13, 4264-4272.
  25. Christian, G.; Stranger, R.; Yates, B. F.; Cummins, C. C., Rationalizing the different products in the reaction of N2 with three-coordinate MoL3 complexes. Dalton Trans. 2007, 1939-1947.
  26. Fox, A. R.; Clough, C. R.; Piro, N. A.; Cummins, C. C., A terminal nitride-to-phosphide conversion sequence followed by tungsten phosphide functionalization using a diphenylphosphenium synthon. Angew. Chem. Int. Ed. 2007, 46, 973-976.
  27. Piro, N. A.; Cummins, C. C., Ethylenebis(triphenylphosphine)platinum as a probe for niobium-mediated diphosphorus chemistry. Inorg. Chem. 2007, 46, 7387-7393.
  28. Cummins, C. C., Terminal, anionic carbide, nitride, and phosphide transition-metal complexes as synthetic entries to low-coordinate phosphorus derivatives. Angew. Chem. Int. Ed. 2006, 45, 862-870.
  29. Curley, J. J.; Sceats, E. L.; Cummins, C. C., A cycle for organic nitrile synthesis via dinitrogen cleavage. J. Am. Chem. Soc. 2006, 128, 14036-14037.
  30. Figueroa, J. S.; Cummins, C. C., A niobaziridine hydride system for white phosphorus or dinitrogen activation and N- or P-atom transfer. Dalton Trans. 2006, 2161-2168.
  31. Figueroa, J. S.; Piro, N. A.; Clough, C. R.; Cummins, C. C., A nitridoniobium(V) reagent that effects acid chloride to organic nitrile conversion: Synthesis via heterodinuclear (Nb/Mo) dinitrogen cleavage, mechanistic insights, and recycling. J. Am. Chem. Soc. 2006, 128, 940-950.
  32. McDonough, J. E.; Weir, J. J.; Sukcharoenphon, K.; Hoff, C. D.; Kryatova, O. P.; Rybak-Akimova, E. V.; Scott, B. L.; Kubas, G. J.; Mendiratta, A.; Cummins, C. C., Comparison of thermodynamic and kinetic aspects of oxidative addition of PhEEPh (E = S, Se, Te) to Mo(CO)3(PR3)2, W(CO)3(PR3)2, and Mo(N[tBu]Ar)3 complexes. The role of oxidation state and ancillary ligands in metal complex induced chalcogenyl radical generation. J. Am. Chem. Soc. 2006, 128, 10295-10303.
  33. Mendiratta, A.; Cummins, C. C.; Kryatova, O. P.; Rybak-Akimova, E. V.; McDonough, J. E.; Hoff, C. D., Benzonitrile extrusion from molybdenum(IV) ketimide complexes obtained via radical C-E (E = O, S, Se) bond formation: Toward a new nitrogen atom transfer reaction. J. Am. Chem. Soc. 2006, 128, 4881-4891.
  34. Mendiratta, A.; Cummins, C. C.; Cotton, F. A.; Ibragimov, S. A.; Murillo, C. A.; Villagrán, D., A diamagnetic dititanium(III) paddlewheel complex with no direct metal-metal bond. Inorg. Chem. 2006, 45, 4328-4330.
  35. Piro, N. A.; Figueroa, J. S.; McKellar, J. T.; Cummins, C. C., Triple-bond reactivity of diphosphorus molecules. Science 2006, 313, 1276-1279.
  36. Cherry, J.-P. F.; Diaconescu, P. L.; Cummins, C. C., Portability of the RNNMo(3+) core - Application to the synthesis of dinitrogen-derived trialkoxymolybdenum organodiazenido complexes. Can. J. Chem. 2005, 83, 302-307.
  37. Figueroa, J. S.; Cummins, C. C., Triatomic EP2 triangles (E = Ge, Sn, Pb) as μ2:η3,η3 bridging ligands. Angew. Chem. Int. Ed. 2005, 44, 4592-4596.
  38. McDonough, J. E.; Weir, J. J.; Carlson, M. J.; Hoff, C. D.; Kryatova, O. P.; Rybak-Akimova, E. V.; Clough, C. R.; Cummins, C. C., Solution calorimetric and stopped-flow kinetic studies of the reaction of ·Cr(CO)3C5Me5 with PhSeSePh and PhTeTePh. experimental and theoretical estimates of the Se-Se, Te-Te, H-Se, and H-Te bond strengths. Inorg. Chem. 2005, 44, 3127-3136.
  39. Mendiratta, A.; Cummins, C. C., Heterobimetallic reductive cross-coupling of benzonitrile with carbon dioxide, pyridine, and benzophenone. Inorg. Chem. 2005, 44, 7319-7321.
  40. Mendiratta, A.; Figueroa, J. S.; Cummins, C. C., Synthesis of a four-coordinate titanium(IV) oxoanion via deprotonation and decarbonylation of complexed formate. Chem. Commun. 2005, 3403-3405.
  41. Murahashi, T.; Clough, C. R.; Figueroa, J. S.; Cummins, C. C., A ligand composed of dinitrogen and methyldiphenylphosphane in a cationic molybdenum complex. Angew. Chem. Int. Ed. 2005, 44, 2560-2563.
  42. Stephens, F. H.; Johnson, M. J. A.; Cummins, C. C.; Kryatova, O. P.; Kryatov, S. V.; Rybak-Akimova, E. V.; McDonough, J. E.; Hoff, C. D., Mechanism of white phosphorus activation by three-coordinate molybdenum(III) complexes: A thermochemical, kinetic, and quantum chemical investigation. J. Am. Chem. Soc. 2005, 127, 15191-15200.
  43. Clough, C. R.; Greco, J. B.; Figueroa, J. S.; Diaconescu, P. L.; Davis, W. M.; Cummins, C. C., Organic nitriles from acid chlorides: An isovalent N for (O)Cl exchange reaction mediated by a tungsten nitride complex. J. Am. Chem. Soc. 2004, 126, 7742-7743.
  44. Figueroa, J. S.; Cummins, C. C., Diorganophosphanylphosphinidenes as complexed ligands: Synthesis via an anionic terminal phosphide of niobium. Angew. Chem. Int. Ed. 2004, 43, 984-988.
  45. Figueroa, J. S.; Cummins, C. C., Phosphaalkynes from acid chlorides via P for O(Cl) metathesis: A recyclable niobium phosphide (P3-) reagent that effects C—P triple-bond formation. J. Am. Chem. Soc. 2004, 126, 13916-13917.
  46. Sceats, E. L.; Figueroa, J. S.; Cummins, C. C.; Loening, N. M.; Van der Wel, P.; Griffin, R. G., Complexes obtained by electrophilic attack on a dinitrogen-derived terminal molybdenum nitride: electronic structure analysis by solid state CP/MAS 15N NMR in combination with DFT calculations. Polyhedron 2004, 23, 2751-2768.
  47. Soo, H. S.; Figueroa, J. S.; Cummins, C. C., A homoleptic molybdenum(IV) enolate complex: Synthesis, molecular and electronic structure, and NCN group transfer to form a terminal cyanoimide of molybdenum(VI). J. Am. Chem. Soc. 2004, 126, 11370-11376.
  48. Soo, H. S.; Diaconescu, P. L.; Cummins, C. C., A sterically demanding enolate ligand: Tantalum ligation and pyridine coupling. Organometallics 2004, 23, 498-503.
  49. Stephens, F. H.; Figueroa, J. S.; Cummins, C. C.; Kryatova, O. P.; Kryatov, S. V.; Rybak-Akimova, E. V.; McDonough, J. E.; Hoff, C. D., Small-molecule activation by molybdaziridine hydride complexes: Mechanistic sequence of the small-molecule binding and molybdaziridine ring-opening steps. Organometallics 2004, 23, 3126-3138.
  50. Wang, J.; Li, S.; Zheng, C.; Li, A.; Hosmane, N. S.; Maguire, J. A.; Roesky, H. W.; Cummins, C. C.; Kaim, W., Chemistry of C-trimethylsilyl-substituted heterocarboranes. 30. Synthetic and structural studies on oxide ion encapsulating tetralanthanide tetrahedra surrounded by “carbons apart” C2B4-carborane ligands (Ln(III) = La, Nd, Gd, Tb, Ho, Lu). Organometallics 2004, 23, 4621-4629.
  51. Blackwell, J. M.; Figueroa, J. S.; Stephens, F. H.; Cummins, C. C., Enediynes via sequential acetylide reductive coupling and alkyne metathesis: Easy access to well-defined molybdenum initiators for alkyne metathesis. Organometallics 2003, 22, 3351-3353.
  52. Figueroa, J. S.; Cummins, C. C., The niobaziridine-hydride functional group: Synthesis and divergent reactivity. J. Am. Chem. Soc. 2003, 125, 4020-4021.
  53. Mendiratta, A.; Cummins, C. C.; Kryatova, O. P.; Rybak-Akimova, E. V.; McDonough, J. E.; Hoff, C. D., Molybdenum chalcogenobenzimidato complexes: Radical synthesis and nitrile extrusion via EPh (E = S, Se, and Te) elimination. Inorg. Chem. 2003, 42, 8621-8623.
  54. Neculai, A.-M.; Cummins, C. C.; Neculai, D.; Roesky, H. W.; Bunkòczi, G.; Walfort, B.; Stalke, D., Elucidation of a Sc(I) complex by DFT calculations and reactivity studies. Inorg. Chem. 2003, 42, 8803-8810.
  55. Stephens, F. H.; Figueroa, J. S.; Diaconescu, P. L.; Cummins, C. C., Molybdenum-phosphorus triple bond stabilization by ancillary alkoxide ligation: Synthesis and structure of a terminal phosphide tris-1-methylcyclohexanoxide complex. J. Am. Chem. Soc. 2003, 125, 9264-9265.
  56. Tsai, Y.-C.; Cummins, C. C., Base-catalyzed dinitrogen cleavage by molybdenum amides. Inorg. Chim. Acta 2003, 345, 63-69.
  57. Tsai, Y.-C.; Stephens, F. H.; Meyer, K.; Mendiratta, A.; Gheorghiu, M. D.; Cummins, C. C., Reactions of organic nitriles with a three-coordinate molybdenum(III) complex and with a related molybdaziridine-hydride. Organometallics 2003, 22, 2902-2913.
  58. Wang, J.; Li, S.; Zheng, C.; Hosmane, N. S.; Maguire, J. A.; Roesky, H. W.; Cummins, C. C.; Kaim, W., An oxide ion encapsulating tetraholmium tetrahedron stabilized by complexation with the “carbons apart” C2B4-carborane ligands. Organometallics 2003, 22, 4390-4392.
  59. Diaconescu, P. L.; Cummins, C. C., Diuranium inverted sandwiches involving naphthalene and cyclooctatetraene. J. Am. Chem. Soc. 2002, 124, 7660-7661.
  60. Agapie, T.; Diaconescu, P. L.; Cummins, C. C., Methine (CH) transfer via a chlorine atom abstraction/benzene-elimination strategy: Molybdenum methylidyne synthesis and elaboration to a phosphaisocyanide complex. J. Am. Chem. Soc. 2002, 124, 2412-2413.
  61. Agapie, T.; Diaconescu, P. L.; Mindiola, D. J.; Cummins, C. C., Radical scission of symmetrical 1,4-dicarbonyl compounds: C—C bond cleavage with titanium(IV) enolate formation and related reactions. Organometallics 2002, 21, 1329-1340.
  62. Brask, J. K.; Durà-Vilà, V.; Diaconescu, P. L.; Cummins, C. C., Vanadium nitride functionalization and denitrogenation by carbon disulfide and dioxide. Chem. Commun. 2002, 902-903.
  63. Diaconescu, P. L.; Odom, A. L.; Agapie, T.; Cummins, C. C., Uranium-group 14 element single bonds: Isolation and characterization of a uranium(IV) silyl species. Organometallics 2001, 20, 4993-4995.
  64. Cherry, J.-P. F.; Johnson, A. R.; Baraldo, L. M.; Tsai, Y.-C.; Cummins, C. C.; Kryatov, S. V.; Rybak-Akimova, E. V.; Capps, K. B.; Hoff, C. D.; Haar, C. M.; Nolan, S. P., On the origin of selective nitrous oxide N—N bond cleavage by three-coordinate molybdenum(III) complexes. J. Am. Chem. Soc. 2001, 123, 7271-7286.
  65. Cherry, J.-P. F.; Stephens, F. H.; Johnson, M. J. A.; Diaconescu, P. L.; Cummins, C. C., Terminal phosphide and dinitrogen molybdenum compounds obtained from pnictide-bridged precursors. Inorg. Chem. 2001, 40, 6860-6862.
  66. Brask, J. K.; Fickes, M. G.; Sangtrirutnugul, P.; Durà-Vilà, V.; Odom, A. L.; Cummins, C. C., Niobium and vanadium iminophosphinimide complexes. Chem. Commun. 2001, 1676-1677.
  67. Mindiola, D. J.; Tsai, Y.-C.; Hara, R.; Chen, Q.; Meyer, K.; Cummins, C. C., Bimetallic μ-cyanoimide complexes prepared by NCN group transfer. Chem. Commun. 2001, 125-126.
  68. Mindiola, D. J.; Cummins, C. C., Probing the niobium metallaaziridine functionality. Organometallics 2001, 20, 3626-3628.
  69. Barybin, M. V.; Diaconescu, P. L.; Cummins, C. C., Coordination chemistry of a chelating amidoximato ligand. Inorg. Chem. 2001, 40, 2892-2897.
  70. Greco, J. B.; Peters, J. C.; Baker, T. A.; Davis, W. M.; Cummins, C. C.; Wu, G., Atomic carbon as a terminal ligand: Studies of a carbidomolybdenum anion featuring solid-state 13C NMR data and proton-transfer self-exchange kinetics. J. Am. Chem. Soc. 2001, 123, 5003-5013
  71. Meyer, K.; Mindiola, D. J.; Baker, T. A.; Davis, W. M.; Cummins, C. C., Uranium hexakisamido complexes. Angew. Chem. Int. Ed. 2000, 39, 3063-3066.
  72. Diaconescu, P. L.; Arnold, P. L.; Baker, T. A.; Mindiola, D. J.; Cummins, C. C., Arene-bridged diuranium complexes: Inverted sandwiches supported by δ-backbonding. J. Am. Chem. Soc. 2000, 122, 6108-6109.
  73. Mindiola, D. J.; Meyer, K.; Cherry, J.-P. F.; Baker, T. A.; Cummins, C. C., Dinitrogen cleavage stemming from a heterodinuclear niobium/molybdenum N2 complex: New nitridoniobium systems including a niobazene cyclic trimer. Organometallics 2000, 19, 1622-1624.
  74. Tsai, Y.-C.; Diaconescu, P. L.; Cummins, C. C., Facile synthesis of trialkoxymolybdenum(VI) alkylidyne complexes for alkyne metathesis. Organometallics 2000, 19, 5260-5262.
  75. Agapie, T.; Odom, A. L.; Cummins, C. C., In pursuit of the molybdenum(III) tris(thiolate) fragment: Unusual structure of a dimolybdenum μ-nitrido complex. Inorg. Chem. 2000, 39, 174-179.
  76. Brock, J. R.; Odom, A. L.; Klei, S. R.; Cummins, C. C., Synthesis and characterization of an organochromium compound bearing three sterically demanding alkenyl ligands. Organometallics 1999, 18, 1360-1362.
  77. Odom, A. L.; Mindiola, D. J.; Cummins, C. C., A nucleophilic chromium(V) dioxo radical anion. Inorg. Chem. 1999, 38, 3290-3295.
  78. Tsai, Y.-C.; Johnson, M. J. A.; Mindiola, D. J.; Cummins, C. C.; Klooster, W. T.; Koetzle, T. F., A cyclometalated resting state for a reactive molybdenum amide: Favorable consequences of β-hydrogen elimination including reductive cleavage, coupling, and complexation. J. Am. Chem. Soc. 1999, 121, 10426-10427.
  79. Peters, J. C.; Cherry, J.-P. F.; Thomas, J. C.; Baraldo, L.; Mindiola, D. J.; Davis, W. M.; Cummins, C. C., Redox-catalyzed binding of dinitrogen by molybdenum N-tert-hydrocarbylanilide complexes: Implications for dinitrogen functionalization and reductive cleavage. J. Am. Chem. Soc. 1999, 121, 10053-10067.
  80. Peters, J. C.; Baraldo, L. M.; Baker, T. A.; Johnson, A. R.; Cummins, C. C., Dimolybdenum-μ-cyanide complexes supported by N-tert-butylanilide ligation: in pursuit of cyanide reductive cleavage. J. Organomet. Chem. 1999, 591, 24-35.
  81. Johnson, A. R.; Davis, W. M.; Cummins, C. C.; Serron, S.; Nolan, S. P.; Musaev, D. G.; Morokuma, K., Four-coordinate molybdenum chalcogenide complexes relevant to nitrous oxide N-N bond cleavage by three-coordinate molybdenum(III): Synthesis, characterization, reactivity, and thermochemistry. J. Am. Chem. Soc. 1998, 120, 2071-2085.
  82. Odom, A. L.; Arnold, P. L.; Cummins, C. C., Heterodinuclear uranium/molybdenum dinitrogen complexes. J. Am. Chem. Soc. 1998, 120, 5836-5837.
  83. Mindiola, D. J.; Cummins, C. C., Deprotonated 2,3:5,6-dibenzo-7-aza bicyclo[2.2.1]hepta-2,5-diene as a nitrido nitrogen source by anthracene elimination: Synthesis of an iodide(nitride)chromium(VI) complex. Angew. Chem. Int. Ed. 1998, 37, 945-947.
  84. Johnson, A. R.; Cummins, C. C.; Gambarotta, S., N-tert-alkylanilides as bulky ancillary ligands. Inorg. Synth. 1998, 32, 123-132.
  85. Odom, A. L.; Cummins, C. C., Chromium(VI) nitrido complexes: reactions with Brønsted acids and synthesis of organometallic derivatives. Polyhedron 1998, 17, 675-688.
  86. Cummins, C. C., Three-coordinate complexes of “hard” ligands: advances in synthesis, structure and reactivity. Prog. Inorg. Chem. 1998, 47, 685-836.
  87. Cummins, C. C., Reductive cleavage and related reactions leading to molybdenum-element multiple bonds: new pathways offered by three-coordinate molybdenum(III). Chem. Commun. 1998, 1777-1786.
  88. Kim, E.; Odom, A. L.; Cummins, C. C., Synthesis of mer-trichlorotris(tetrahydrofuran) tungsten(III) by intermetal chlorine atom transfer. Inorg. Chim. Acta 1998, 278, 103-107.
  89. Peters, J. C.; Odom, A. L.; Cummins, C. C., A terminal molybdenum carbide prepared by methylidyne deprotonation. Chem. Commun. 1997, 1995-1996.
  90. Fickes, M. G.; Odom, A. L.; Cummins, C. C., A nucleophilic niobium(V) nitride prepared by isocyanate decarbonylation. Chem. Commun. 1997, 1993-1994.
  91. Johnson, M. J. A.; Lee, P. M.; Odom, A. L.; Davis, W. M.; Cummins, C. C., Atom-bridged intermediates in N- and P-atom transfer reactions. Angew. Chem. Int. Ed. 1997, 36, 87-91.
  92. Johnson, M. J. A.; Odom, A. L.; Cummins, C. C., Phosphorus monoxide as a terminal ligand. Chem. Commun. 1997, 1523-1524.
  93. Johnson, A. R.; Davis, W. M.; Cummins, C. C., Titanium complexes stabilized by N-(tert-hydrocarbyl)anilide ligation: a synthetic investigation. Organometallics1996, 15, 3825-3835.
  94. Laplaza, C. E.; Johnson, A. R.; Cummins, C. C., Nitrogen atom transfer coupled with dinitrogen cleavage and MoMo triple bond formation. J. Am. Chem. Soc. 1996, 118, 709-710.
  95. Laplaza, C. E.; Johnson, M. J. A.; Peters, J. C.; Odom, A. L.; Kim, E.; Cummins, C. C.; George, G. N.; Pickering, I. J., Dinitrogen cleavage by three-coordinate molybdenum(III) complexes: Mechanistic and structural data. J. Am. Chem. Soc. 1996, 118, 8623-8638.
  96. Odom, A. L.; Cummins, C. C., A chromium(VI) nitrido-silylmethyl complex and a chromium(V) μ-nitrido dimer: Synthetic and structural details. Organometallics 1996, 15, 898-900.
  97. Peters, J. C.; Johnson, A. R.; Odom, A. L.; Wanandi, P. W.; Davis, W. M.; Cummins, C. C., Assembly of molybdenum/titanium μ-oxo complexes via radical alkoxide C—O cleavage. J. Am. Chem. Soc. 1996, 118, 10175-10188.
  98. Schaller, C. P.; Cummins, C. C.; Wolczanski, P. T., Hydrocarbon activation via reversible 1,2-RH-elimination from (tBu3SiNH)3ZrR: Synthetic, structural, and mechanistic investigations. J. Am. Chem. Soc. 1996, 118, 591-611.
  99. Schrock, R. R.; Cummins, C. C.; Wilhelm, T.; Lin, S.; Reid, S. M.; Kol, M.; Davis, W. M., Synthesis of titanium complexes that contain triamido-amine ligands. Organometallics 1996, 15, 1470-1476.
  100. Stokes, S. L.; Davis, W. M.; Odom, A. L.; Cummins, C. C., Low-coordinate iron complexes stabilized by N-(tert-hydrocarbyl)anilide ligation: Adduct formation, chemical oxidation, and nitric oxide complexation. Organometallics 1996, 15, 4521-4530.
  101. Wu, G.; Rovnyak, D.; Johnson, M. J. A.; Zanetti, N. C.; Musaev, D. G.; Morokuma, K.; Schrock, R. R.; Griffin, R. G.; Cummins, C. C., Unusual 31P chemical shielding tensors in terminal phosphido complexes containing a phosphorus-metal triple bond. J. Am. Chem. Soc. 1996, 118, 10654-10655.
  102. Fickes, M. G.; Davis, W. M.; Cummins, C. C., Isolation and structural characterization of the terminal mesityl azide complex V(N3Mes)(I)(NRArF)2 and its conversion to a vanadium(V) imido complex. J. Am. Chem. Soc. 1995, 117, 6384-6385.
  103. Odom, A. L.; Cummins, C. C.; Protasiewicz, J. D., Nitric oxide cleavage: Synthesis of terminal chromium(VI) nitrido complexes via nitrosyl deoxygenation. J. Am. Chem. Soc. 1995, 117, 6613-6614.
  104. Wanandi, P. W.; Davis, W. M.; Cummins, C. C.; Russell, M. A.; Wilcox, D. E., Radical synthesis of a heterobinuclear μ-oxo complex: Reaction of V(O)(O-i-Pr)3 with Ti(NRAr)3 (R = C(CD3)2CH3, Ar = 3,5-C6H3Me2). J. Am. Chem. Soc. 1995, 117, 2110-2111.
  105. Laplaza, C. E.; Davis, W. M.; Cummins, C. C., A molybdenum-phosphorus triple bond: Synthesis, structure, and reactivity of the terminal phosphido (P3-) complex [Mo(P)(NRAr)3]. Angew. Chem. Int. Ed. 1995, 34, 2042-2044.
  106. Laplaza, C. E.; Cummins, C. C., Dinitrogen cleavage by a three-coordinate molybdenum(III) complex. Science 1995, 268, 861-863.
  107. Laplaza, C. E.; Odom, A. L.; Davis, W. M.; Cummins, C. C.; Protasiewicz, J. D., Cleavage of the nitrous oxide NN bond by a three-coordinate molybdenum(III) complex. J. Am. Chem. Soc. 1995, 117, 4999-5000.
  108. Laplaza, C. E.; Davis, W. M.; Cummins, C. C., Tin N-tert-butylanilide compounds. Organometallics 1995, 14, 577-580.
  109. Johnson, A. R.; Wanandi, P. W.; Cummins, C. C.; Davis, W. M., Cleavage of titanium dimethylamides with methyl iodide. Organometallics 1994, 13, 2907-2909.
  110. Freundlich, J. S.; Schrock, R. R.; Cummins, C. C.; Davis, W. M., Organometallic complexes of tantalum that contain the triamidoamine ligand, [(Me3SiNCH2CH2)3N]3-, including an ethylidene complex formed via a phosphine-catalyzed rearrangement of an ethylene complex. J. Am. Chem. Soc. 1994, 116, 6476-6477.
  111. Cummins, C. C.; Schrock, R. R.; Davis, W. M., Synthesis of terminal vanadium(V) imido, oxo, sulfido, selenido, and tellurido complexes by imido group or chalcogenide atom transfer to trigonal monopyramidal V[N3N] (N3N = [(Me3SiNCH2CH2)3N]3-). Inorg. Chem. 1994, 33, 1448-1457.
  112. Cummins, C. C.; Schrock, R. R., Synthesis of an iron(IV) cyanide complex that contains the triamido amine ligand [(tert-BuMe2SiNCH2CH2)3N]3-. Inorg. Chem. 1994, 33, 395-396.
  113. Cummins, C. C.; Schrock, R. R.; Davis, W. M., Phosphinidenetantalum(V) complexes of the type [(N3N)Ta=PR] as phospha-Wittig reagents. Angew. Chem. Int. Ed. 1993, 32, 756-759.
  114. Cummins, C. C.; Lee, J.; Schrock, R. R.; Davis, W. M., Trigonal-Monopyramidal MIII Complexes of the Type [M(N3N)] (M = Ti, V, Cr, Mn, Fe; N3N = (tert-BuMe2SiNCH2CH2)3N). Angew. Chem. Int. Ed. 1992, 31, 1501-1503.
  115. Cummins, C. C.; Schrock, R. R.; Davis, W. M., Synthesis of vanadium and titanium complexes of the type RM[(Me3SiNCH2CH2)3N] (R = Cl, alkyl) and the structure of ClV[(Me3SiNCH2CH2)3N]. Organometallics 1992, 11, 1452-1454.
  116. Cummins, C. C.; Schrock, R. R.; Cohen, R. E., Synthesis of zinc sulfide and cadmium sulfide within ROMP block copolymer microdomains. Chem. Mater. 1992, 4, 27-30.
  117. Sankaran, V.; Cohen, R. E.; Cummins, C. C.; Schrock, R. R., Morphology of diblock copolymers of norbornene and organometallic derivatives of norbornene. Macromolecules 1991, 24, 6664-6669.
  118. Cummins, C. C.; Schrock, R. R.; Davis, W. M., Synthesis of cadmium pentamethylcyclopentadienyl complexes. Organometallics 1991, 10, 3781-3785.
  119. Cummins, C. C.; Schaller, C. P.; Van Duyne, G. D.; Wolczanski, P. T.; Chan, A. W. E.; Hoffmann, R., Tri-tert-butylsilyl)imido complexes of titanium: benzene carbon-hydrogen activation and structure of [(tert-Bu3SiNH)Ti]2(μ-NSi-tert-Bu3)2. J. Am. Chem. Soc. 1991, 113, 2985-2994.
  120. Cummins, C. C.; Beachy, M. D.; Schrock, R. R.; Vale, M. G.; Sankaran, V.; Cohen, R. E., Synthesis of norbornenes containing tin(II), tin(IV), lead(II), and zinc(II) and their polymerization to give microphase-separated block copolymers. Chem. Mater. 1991, 3, 1153-1163.
  121. Cummins, C. C.; Van Duyne, G. D.; Schaller, C. P.; Wolczanski, P. T., Carbonylation of zirconium complex [tert-Bu3SiNH]3ZrH and x-ray structural study of [tert-Bu3SiNH]3ZrMe. Organometallics 1991, 10, 164-170.
  122. Sankaran, V.; Cummins, C. C.; Schrock, R. R.; Cohen, R. E.; Silbey, R. J., Small lead sulfide (PbS) clusters prepared via ROMP block copolymer technology. J. Am. Chem. Soc. 1990, 112, 6858-6859.
  123. Cummins, C. C.; Baxter, S. M.; Wolczanski, P. T., Methane and benzene activation via transient (tert-Bu3SiNH)2Zr=NSi-tert-Bu3. J. Am. Chem. Soc. 1988, 110, 8731-8733.


Some good links:
Inorganic Syntheses / ACS Journals / ACIE


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