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Application of Allenylsilanes in Synthesis of Homopropargylic Alcohols

References:

"Trimethylsilylallenes as Propargylic Anion Equivalents: Synthesis of Homopropargylic Alcohols and Ethers", R. L. Danheiser and D. J. Carini, J. Org. Chem. 1980, 45, 3925.

"Scope and Stereochemical Course of the Addition of Allenylsilanes to Ketones and Aldehydes.  A Regiocontrolled Synthesis of Homopropargylic Alcohols", R. L. Danheiser, D. J. Carini, and C. A. Kwasigroch, J. Org. Chem. 1986, 51, 3870.

[ Home ] [ [2 + 2 + 2] Cycloaddition Strategies ] [ [3 + 2] Annulations of Organosilanes ] [ Vinylcyclopropane Rearrangements ] [ Cycloadditions and Annulations of Vinylketenes ] [ Highly Unsaturated, Conjugated Molecules ] [ [4 + 2] Cycloadditions of Imine Derivatives ] [ Ketene [2 + 2] Cycloadditions ] [ Acylsilanes ] [ B-Lactones ] [ Cyclopropylboranes ] [ Allenylsilanes and Homopropargylic Alcohols ] [ Cationic Cyclizations ] [ Synthesis of Azulenes ] [ Miscellaneous Synthetic Methods ]