Publications Go to Complete List of Publications Selected Publications: “Total Synthesis of (-)-Voacinol and (-)-Voacandimine C.” Flynn, K. M.; Myeong, I.-S.; Pinto, T.; Movassaghi, M. J. Am. Chem. Soc. 2022, 144, 91269131. “Total Synthesis and Stereochemical Assignment of ()-Psychotridine.” Scott, T. Z.; Armelin, V. F.; Movassaghi, M. Org. Lett. 2022, 24, 21602164. “Total Synthesis of Himastatin.” DAngelo, K.; Schissel, C.; Pentelute, B.; Movassaghi, M. Science 2022, 375, 894899. “Structure and Function of NzeB, a Versatile CC and CN Bond Forming Diketopiperazine Dimerase.” Shende, V. V.; Khatray, Y.; Newmister, S. A.; Sanders, J.; Lindovska, P.; Yu, F.; Doyon, T.; Houk. K. N.; Movassaghi, M.; Sherman, D. H. J. Am. Chem. Soc. 2020, 142, 1741317424. “n→π* Interactions modulate the disulfide reduction potential of epidithiodiketopiperazines.” Kilgore, H. R.; Olsson, C. R.; D'Angelo, K. A.; Movassaghi, M.; Raines, R. T. J. Am. Chem. Soc. 2020, 142, 1510715115. “Synthesis of Potent Cytotoxic Epidithiodiketopiperazines Designed for Derivatization.” Olsson, C. R.; Payette, J. N.; Cheah, J. H.; Movassaghi, M. J. Org. Chem. 2020, 85, 46484662. “Total Synthesis and Anti-Cancer Activity of All Known Communesin Alkaloids and Related Derivatives.” Pompeo, M. M.; Cheah, J. H.; Movassaghi, M. J. Am. Chem. Soc. 2019, 141, 1441114420. “Mechanism of Permanganate Promoted Dihydroxylation of Complex Diketopiperazines: Critical Roles of Counter-Cation and Ion-Pairing.” Haines, B. E.; Nelson, B. M.; Grandner, J. M; Kim, J.; Houk, K. N; Movassaghi, M.; Musaev, D. G. J. Am. Chem. Soc. 2018, 140 (41), 1337513386. “Concise Synthesis of (–)-Hodgkinsine, (–)-Calycosidine, (–)-Hodgkinsine B, (–)-Quadrigemine C, and (–)-Psycholeine via Convergent and Directed Modular Assembly of Cyclotryptamines.” Lindovska, P.; Movassaghi, M. J. Am. Chem. Soc. 2017 139 (48), 1759017596. “Quantitative Modeling of Bis(pyridine)silver (I) Permanganate Oxidation of Hydantoin Derivatives: Guidelines for Predicting the Site of Oxidation in Complex Substrates.” Bischoff, A. J.; Nelson, B. M.; Niemeyer, Z. L.; Sigman, M. S.; Movassaghi, M. J. Am. Chem. Soc. 2017, 139 (43), 1553915547. “Enantioselective Total Synthesis of (–)-Deoxoapodine.” Kang, T.; White, K. L.; Mann, T. J.; Hoveyda, A. H.; Movassaghi, M. Angew. Chem. Int. Ed. 2017, 56, 13857 “Synthesis and Evaluation of Agelastatin Derivatives as Potent Modulators for Cancer Invasion and Metastasis.” Antropow, A. H.; Xu, K.; Buchsbaum, R. J.; Movassaghi, M. J. Org. Chem. 2017, 82, 77207731. “Concise Total Syntheses of (+)-Haplocidine and (+)-Haplocine Via Late-Stage Oxidation of (+)-Fendleridine Derivatives.” White, K. L.; Movassaghi, M. J. Am. Chem. Soc. 2016, 138, 1138311389. “Convergent and Biomimetic Enantioselective Total Synthesis of (−)-Communesin F.” Lathrop, S. P.; Pompeo, M.; Chang, W.-T. T.; Movassaghi, M. J. Am. Chem. Soc. 2016, 138, 77637769. “Concise Total Synthesis of (+)-Asperazine, (+)-Pestalazine A, and (+)-iso-Pestalazine A. Structure Revision of (+)-Pestalazine A.” Loach, R. P.; Fenton, O. S.; Movassaghi, M. J. Am. Chem. Soc. 2016, 138, 10571064. “The fibroblast Tiam1-osteopontin pathway modulates breast cancer invasion and metastasis.” Xu, K.; Tian, X.; Oh, S. Y.; Movassaghi, M.; Naber, S. P.; Kuperwasser, C.; Buchsbaum, R. J. Breast Cancer Res. 2016, 18, 14. “Direct Observations of Intermediates Involved in the Bischler-Napieralski Reaction.” White, K. L.; Mewald, M.; Movassaghi, M. J. Org. Chem. 2015, 80, 74037411. “Biogenetically-Inspired Total Synthesis of Epidithiodiketopiperazines and Related Alkaloids.” Kim, J.; Movassaghi, M. Acc. Chem. Res. 2015, 48, 11591171. “Concise and Enantioselective Total Synthesis of (−)-Mehranine, (−)-Methylenebismehranine, and Related Aspidosperma Alkaloids.” Mewald, M.; Medley, J. W.; Movassaghi, M. Angew. Chem. Int. Ed. 2014, 53, 1163411639. “Application of Diazene-Directed Fragment Assembly to the Total Synthesis and Stereochemical Assignment of (+)-Desmethyl-meso-chimonanthine and Related Heterodimeric Alkaloids ” Lathrop, S. P.; Movassaghi, M. Chem. Sci. 2014, 5, 333340. “Synthesis and Anticancer Activity of all known (−)-Agelastatin Alkaloids.” Han, S.; Siegel, D. S.; Morrison, K. C.; Hergenrother, P. J.; Movassaghi, M. J. Org. Chem. 2013, 78, 1197011984. “Concise Total Synthesis of (+)-Bionectins A and C” Coste, A.; Kim, J.; Adams, T. C.; Movassaghi, M. Chem. Sci. 2013, 4, 31913197. “Synthesis and Anticancer Activity of Epipolythiodiketopiperazine Alkaloids ” Boyer, N.; Morrison, K. C.; Kim, J.; Hergenrother, P. J.; Movassaghi, M. Chem. Sci. 2013, 4, 16461657. “A Concise and Versatile Double-Cyclization Strategy for the Highly Stereoselective Synthesis and Arylative Dimerization of Aspidosperma Alkaloids.” Medley, J. W.; Movassaghi, M. Angew. Chem. Int. Ed. 2012, 51, 45724576. “Concise Total Synthesis and Stereochemical Revision of (+)-Naseseazines A and B: Regioselective Arylative Dimerization of Diketopiperazine Alkaloids.” Kim, J.; Movassaghi, M. J. Am. Chem. Soc. 2011, 133, 1494014943. “Directed Heterodimerization: Stereocontrolled Assembly via Solvent-Caged Unsymmetrical Diazene Fragmentation.” Movassaghi, M.; Ahmad, O. K.; Lathrop, S. P. J. Am. Chem. Soc. 2011, 133, 1300213005. “Concise Total Synthesis and Stereochemical Revision of all (−)-Trigonoliimines.” Han, S.; Movassaghi, M. J. Am. Chem. Soc. 2011, 133, 1076810771. “General Approach to Epipolythiodiketopiperazine Alkaloids: Total Synthesis of (+)-Chaetocins A and C and (+)-12,12'-Dideoxychetracin A.” Kim, J.; Movassaghi, M. J. Am. Chem. Soc. 2010, 132, 1437614378. “Total Synthesis of All (–)-Agelastatin Alkaloids.” Movassaghi, M.; Siegel, D. S.; Han, S. Chemical Science 2010, 1, 561-566. “Total Synthesis of (-)-Himandrine.” Movassaghi, M.; Tjandra, M.; Qi, J. J. Am. Chem. Soc. 2009, 131, 96489650. “Total Synthesis of (+)-11,11'-Dideoxyverticillin A.” Kim, J.; Ashenhurst, J. A.; Movassaghi, M. Science 2009, 324, 238241. “Stereospecific Palladium-Catalyzed Entry to Monoalkyl Diazenes for Mild Allylic Reduction.” Movassaghi, M.; Ahmad, O. K. Angew. Chem. Int. Ed. 2008, 47, 89098912. “Concise Total Synthesis of (+)-WIN 64821 and (–)-Ditryptophenaline.” Movassaghi, M.; Schmidt, M. A.; Ashenhurst, J. A. Angew. Chem. Int. Ed. 2008, 47, 14851487. “Efficient and Stereoselective Dimerization of Pyrroloindolizine Derivatives Inspired by a Hypothesis for the Biosynthesis of Complex Myrmicarin Alkaloids.” Movassaghi, M.; Ondrus, A. E.; Chen, B. J. Org. Chem. 2007, 72, 1006510074. “Direct Synthesis of Pyridine Derivatives.” Movassaghi, M.; Hill, M. D.; Ahmad, O. K. J. Am. Chem. Soc. 2007, 129, 1009610097. “Concise Total Synthesis of (–)-Calycanthine, (+)-Chimonanthine, and (+)-Folicanthine.” Movassaghi, M.; Schmidt, M. A. Angew. Chem. Int. Ed. 2007, 46, 37253728. “Stereoselective Intermolecular Formal [3+3] Cycloaddition Reaction of Cyclic Enamines and Enones.” Movassaghi, M.; Chen, B. Angew. Chem. Int. Ed. 2007, 46, 565568. “Single-Step Synthesis of Pyrimidine Derivatives.” Movassaghi, M.; Hill, M. D. J. Am. Chem. Soc. 2006, 128, 1425414255. “Enantioselective Total Synthesis of (–)-Acylfulvene and (–)-Irofulven.” Movassaghi, M.; Piizzi, G.; Siegel, D. S.; Piersanti, G. Angew. Chem. Int. Ed. 2006, 45, 58595863. “Total Synthesis and Absolute Stereochemical Assignment of (+)- and (–)-Galbulimima Alkaloid 13.” Movassaghi, M.; Hunt, D. K.; Tjandra, M. J. Am. Chem. Soc. 2006, 128, 81268127.
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