By growing and isolating ultra-long (>1 cm) SWNT, we have been able to form the longest, highest-aspect ratio nanopores ever achieved. With unbroken, persistent interior diameters between 1 and 2 nm, these pores allow us to study transport phenomena on an unprecedented scale.
Using Raman spectroscopy we characterize the pore diameter to within an angstrom prior to forming a device by bonding a polymer barrier across the SWNT to demarcate two reservoirs. We then immerse the channel in aqueous salt solution and apply a bias between the reservoirs, driving an electro-osmotic current via proton conduction. As salt ions enter the channel, they attenuate proton transport, ‘blocking’ the pore via a coulter mechanism and reducing the measured current by a fixed blockade current until they leave after some dwell time. By measuring the blockade current and dwell time for different salts, we have been able to elucidate transport behaviors.
Figure 1. Cartoon of the channel fabrication process Inset: SEM image of SWNT after growth.
Figure 2. Current traces over time during coulter blocking events caused by salt ions
CY Lee, W Choi, J-H Han, MS Strano Science 329 (5997) 2010
W Choi, CY Lee, MH Ham, S Shimizu, MS Strano J. Am. Chem. Soc. 133 (2) 2011
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