DONALD ROBERT SADOWAY
Present Position
John F. Elliott Professor of Materials Chemistry
Department of Materials Science Engineering
Massachusetts Institute of Technology
Address
Massachusetts Institute of Technology, Room 8-203
77 Massachusetts Avenue
Cambridge MA 02139-4307
telephone: 617.253.3487; fax: 617.253.5418; email: dsadoway@mit.edu
Date and Place of Birth
March 7, 1950; Toronto, Ontario, CANADA
Citizenship
United States
Education
Ph.D., Chemical Metallurgy, University of Toronto, 1977
M.A.Sc., Chemical Metallurgy, University
of Toronto, 1973
B.A.Sc., Engineering Science, University
of Toronto, 1972
Awards and Honors
Norwegian Academy of
Technological Sciences, elected Member 2001 -
John F.
Elliott Chair in Chemical Metallurgy, 1999 -
Bose Award for Teaching in the School of Engineering at MIT, 1997
MacVicar Faculty Fellow, 1995 - 2005
AT&T Industrial Ecology Faculty Fellow, 1994 - 1995
MIT Graduate Student Council Teaching Award, 1993, 1988, 1987, 1984, and 1982
Prof. T.B. King Memorial Award, 1986
Alcoa Foundation Professional Development Award, 1980 - 1983
NATO Postdoctoral Research Fellowship, 1977 - 1978
Memberships
The Minerals, Metals, and
Materials Society, TMS
The Electrochemical Society
The Materials Research Society
International Society of Electrochemistry
The Iron and Steel Society
American Association for the Advancement of
Science
Professional Service
Journal of Materials
Research, Principal Editor, 1996 - 2001
Journal
of Light Metals, Member of Editorial Board, 2001 - 2002
Industrial Experience
Dominion Foundries and Steel Co., Ltd., Hamilton, Ontario, summer, 1971.
Research Assistant in the Research Department.
Academic Experience
Professor in the Department of Materials Science and Engineering,
Massachusetts Institute of Technology, 1992 - present. Courses taught:
Introduction to Solid State Chemistry, freshman level; Chemical Metallurgy, senior
level; Kinetic Processes in Materials, graduate level; Electrochemical
Processing of Materials, graduate level.
Associate Professor in the Department of Materials Science and Engineering,
Massachusetts Institute of Technology, 1982 - 1992. Courses taught: as above.
Assistant Professor in the Department of Materials Science and Engineering,
Massachusetts Institute of Technology, 1978 - 1982. Courses taught: as above.
Postdoctoral Fellow in the Department of Materials Science and Engineering,
Massachusetts Institute of Technology, 1977 - 1978.
Teaching Assistant in the Department of Metallurgy and Materials Science, University of Toronto , 1972 - 1976. Courses taught:
Metallurgical Thermodynamics; Kinetics of Metallurgical Processes;
Electrochemistry; all undergraduate level.
Research Interests
Professor Sadoway's research seeks to establish the scientific underpinnings for technologies that make efficient use of energy and natural resources in an environmentally sound manner. This spans engineering applications and the supportive fundamental science. The overarching theme of his work is electrochemistry in nonaqueous media.
Specific topics in applied research are the following: environmentally sound electrochemical extraction and recycling of metals, lithium solid-polymer-electrolyte batteries for portable power, high-amperage energy storage devices for stationary applications, advanced materials for use as electrodes in fused-salt electrolysis cells and batteries, electrochemical synthesis of compound semiconductors, and electrochemical synthesis of diamond coatings.
The related fundamental research is the physical chemistry and electrochemistry of molten salts (including molten oxides), cryogenic electrolytes, and solid polymer electrolytes.
- R.M. Rose and D.R.
Sadoway, inventors and assignees, "Cryoelectrodeposition,"
U.S. patent no. 4,517,253, May 14, 1985; also issued as Can. patent
no. 1,246,001, December 6, 1988.
- D.R. Sadoway, inventor, Massachusetts Institute of Technology,
assignee, "Aluminum Reference
Electrode," U.S. patent no. 4,764,257, August 16, 1988.
- D.R. Sadoway and R.P. Singh,
inventors, Massachusetts Institute of
Technology, assignee, "Method
for Forming a Metal Coating on a Substrate," U.S. patent no.
4,882,199, November 21, 1989.
- D.R. Sadoway and R.M. Rose, inventors,
Massachusetts Institute of Technology,
assignee, "Electrochemically
Controlled Superconductivity," U.S. patent no. 4,911,800, March
27, 1990.
- D.R. Sadoway and R.M. Rose, inventors,
Massachusetts Institute of Technology,
assignee, "Cryoelectrosynthesis,"
U.S. patent no. 4,971,663, November 20, 1990.
- D.R. Sadoway, inventor, Massachusetts Institute of Technology,
assignee, "Apparatus and Method
for the Electrolytic Production of Metals," U.S. patent no. 4,999,097,
March 12, 1991.
- D.R. Sadoway and R.M. Rose, inventors,
Massachusetts Institute of Technology,
assignee, "Methods for Processing
Superconducting Materials," U.S. patent no. 5,166,131, November
24, 1992.
- D.R. Sadoway, inventor, Massachusetts Institute of Technology,
assignee, "Electrolytic Production
of Metals Using Consumable Anodes," U.S. patent no. 5,185,068,
February 9, 1993.
- D.R. Sadoway, inventor, Massachusetts Institute of Technology,
assignee, "Apparatus for the
Electrolytic Production of Metals," U.S. patent no. 5,254,232,
October 19, 1993.
- S.L. Schiefelbein, N.A.
Fried, K.G. Rhoads, and D.R. Sadoway, inventors, Massachusetts Institute of Technology,
assignee, "High Accuracy
Calibration-free Electrical Parameter Measurements," U.S. patent no.
5,489,849, February 6, 1996.
- U.B. Pal and D.R. Sadoway,
inventors, Massachusetts Institute of
Technology, assignee, "Accelerated
Decarburization of Fe-C Metal Alloys," U.S. patent no. 5,632,800,
May 27, 1997.
- A.M. Mayes, D.R. Sadoway, P.
Banerjee, P. Soo, B. Huang, inventors, Massachusetts
Institute of Technology, assignee, "Self-doped
Microphase Separated Block Copolymer Electrolyte," U.S. patent no.
6,361,901, March 26, 2002.
- Y.-M. Chiang, D.R. Sadoway,
Y.-I. Jang, B. Huang, inventors, Massachusetts Institute of Technology,
assignee, “Intercalation compounds
and electrodes for batteries,” U.S. patent no. 6,787,232,
September 7, 2004.
- A.M. Mayes, D.R. Sadoway,
P.P. Soo, B. Huang, inventors, Massachusetts Institute of Technology,
assignee, “Non-crosslinked, Amorphous,
Block Copolymer Electrolyte for Batteries,” U.S. patent no. 7,026,071,
April 11, 2006.
Scientific Papers
- D.R. Sadoway and S.N.
Flengas, "Charge asymmetrical ternary molten salt systems: theory of
dilute solutions," J. Electrochem. Soc., 122, 515
(1975).
- D.R. Sadoway and S.N.
Flengas, "Vapour pressures of solid and liquid NbCl5 and TaCl5," Can. J. Chem., 54,
1692 (1976).
- D.R. Sadoway and S.N.
Flengas, "The synthesis and properties of the hexachloroniobates and
hexachlorotantalates of Na, K, Rb, and Cs," Can. J. Chem., 56,
2013 (1978).
- D.R. Sadoway and S.N.
Flengas, "Thermodynamic properties of the alkalimetal
hexachloroniobate and hexachlorotantalate compounds by vapour pressure
measurements," Can. J. Chem., 56, 2538 (1978).
- D.R. Sadoway and S.N.
Flengas, "A new process for the separation of tantalum from
niobium," Metall. Trans., B., 11B, 57 (1980).
- D.R. Sadoway, S.N. Flengas
and R.G.V. Hancock, "Quantitative determination of tantalum in
niobium by neutron activation analysis," Can. J. Chem., 58,
537 (1980).
- D.R. Sadoway and J. Szekely,
"A New Experimental Technique for the Study of Turbulence in
Electromagnetically Driven Flows," Metall Trans., B., 11B,
334 (1980).
- G.B. Kenney, D.R. Sadoway,
and M.C. Flemings, "An Assessment of the Potential for Magnesium
Penetration of the U.S. Automotive Market," Proc. 37th Ann. World
Conf. on Magnesium, International Magnesium Association, Dayton OH,
1980, pp. 14-18.
- D.R. Sadoway and S.N.
Flengas, "The Thermodynamics of Tantalum/Niobium Separation by
Gas-solid Reaction in Chloride Systems," Extractive Metallurgy of
Refractory Metals, H.Y. Sohn, O.N. Carlson, and J.T. Smith, editors, TMS/AIME, Warrendale PA, 1981, pp. 107-126.
- S.N. Flengas and D.R.
Sadoway, "Thermodynamic Treatment of Ternary and Quarternary Fused
Salt Systems," Molten Salts, Proceedings of Third International
Symposium, G. Mamantov, M. Blander and G.P. Smith, editors, The Electrochemical Society, Pennington
NJ, 1981, pp. 68-94.
- D.R. Sadoway, "Problems
and Research Opportunities in Energy Efficient Metallurgical
Processes," Proceedings of the 16th Intersociety Energy Conversion
Engineering Conference, H. Yeh and J. Snell, editors, ASME, New York, 1981, pp. 579-582.
- M.H. Sukkar and D.R. Sadoway, "Electrical Conductivity and Thermal Stability Measurements of a
Mixed Perovskite Oxide System," J. Appl. Phys., 53,
3686 (1982).
- D.R. Sadoway, "The
Materials Energy Symbiosis," Chemtech, 12 (10), 625
(1982).
- A. Abdelmassih and D.R.
Sadoway, "Laser Schlieren Studies of Aqueous Zinc Chloride
Electrolysis," Chloride Electrometallurgy, P.D. Parker,
editor, TMS/AIME, Warrendale PA, 1983,
pp. 43-57.
- A. Block-Bolten and D.R.
Sadoway, "On Binary P-T Phase Diagrams," Metall. Trans., B,
14B, 231 (1983).
- D.R. Sadoway, "Research
Opportunities in Fused Salt Electrometallurgy," Electrochemistry
Research Needs for Mineral and Primary Materials Processing, T.J.
O'Keefe and J.W. Evans, editors, USBM/NSF,
1983, pp. 163-166.
- R.P. Singh, J.H. Flint, and
D.R. Sadoway, "Digital Signal Analysis of Metal Electroreduction
Cells," Control '84, Proc. 1st International Symp. on Automatic
Control in Mineral Processing and Process Metallurgy, D.G. George et
al., editors, SME/TMS/AIME, Warrendale
PA, 1984, pp. 319-326.
- A.D. McLeod, J.S. Haggerty,
and D.R. Sadoway, "Electrical Resistivities of Monocrystalline and
Polycrystalline TiB2"
J. Am. Ceram. Soc., 67,
705 (1984).
- G.J. Kipouros and D.R.
Sadoway, "Fused Salt Electroplating," Innovations in
Materials Processing, G. Bruggeman and V. Weiss, editors, Plenum Press, New York, 1985, pp. 493-503.
- G.J. Kipouros and D.R.
Sadoway, "Molybdenum Coatings by Molten Salt Electrolysis," Energy
Reduction Techniques in Metal Electrochemical Processes, R.G. Bautista
and R. Wesely, editors, TMS/AIME,
Warrendale PA, 1985, pp. 471-478.
- J.K. Koziol and D.R. Sadoway,
"Electrolyte Flow Patterns in Molten Salt Electrolysis Cells," Energy
Reduction Techniques in Metal Electrochemical Processes, R.G. Bautista
and R. Wesely, editors, TMS/AIME,
Warrendale PA, 1985, pp. 433-444.
- A.D. McLeod, J.S. Haggerty,
and D.R. Sadoway, "Inert Electrodes for Aluminum Electrolysis
Cells," Energy Reduction Techniques in Metal Electrochemical
Processes, R.G. Bautista and R. Wesely, editors, TMS/AIME, Warrendale PA, 1985, pp. 453-456.
- R.P. Singh, J.H. Flint, D.R.
Sadoway, "Digital Signal Analysis of Molten Salt Electrolysis
Cells," Energy Reduction Techniques in Metal Electrochemical
Processes, R.G. Bautista and R. Wesely, editors, TMS/AIME, Warrendale PA, 1985, pp. 155-162.
- S.Y. Yoon, J.H. Flint, G.J.
Kipouros, and D.R. Sadoway, "Raman Scattering Studies of Molten Salt
Electrolysis of Light Metals," Energy Reduction Techniques in
Metal Electrochemical Processes, R.G. Bautista and R. Wesely, editors,
TMS/AIME, Warrendale PA, 1985, pp.
479-490.
- G.J. Kipouros, J.H. Flint,
and D.R. Sadoway, "Raman Spectroscopic Investigation of AlkaliMetal
Hexachloro Compounds of Refractory Metals," Inorg. Chem., 24,
3881, 1985.
- D.R. Sadoway, "Electrometallurgy,"
Encyclopedia of Materials Science and Engineering, M.B. Bever,
editor, Pergamon Press, Oxford, 1986, pp. 1444-1447.
- D.R. Sadoway, "Halide
Metallurgy," Encyclopedia of Materials Science and Engineering,
M.B. Bever, editor, Pergamon Press, Oxford, 1986, pp. 2072-2073.
- A.D. McLeod, J.S. Haggerty,
and D.R. Sadoway, "Inert Anode Materials for Hall Cells," Light
Metals 1986, R.E. Miller, editor, TMS/AIME,
Warrendale PA, 1986, pp. 269-273.
- S.Y. Yoon, Y. Liu, J.H.
Flint, G.J. Kipouros, and D.R. Sadoway, "In Situ Raman Spectroscopic
Investigation of Melt Chemistry and Electrode Processes in Laboratoryscale
Aluminum Cells," Light Metals 1986, R.E. Miller, editor, TMS/AIME, Warrendale PA, 1986, pp. 479-482.
- S.Y. Yoon, J.H. Flint, G.J.
Kipouros, and D.R. Sadoway, "Raman Scattering Studies of Magnesium
Electrolysis," Light Metals 1986, R.E. Miller, editor, TMS/AIME, Warrendale PA, 1986, pp.
1009-1012.
- A.D. McLeod, J.S. Haggerty,
and D.R. Sadoway, "Inert Anode Materials for Hall Cells," Proceedings
of a conversazione on "The Production of Liquid Aluminum,"
E. Ozberk, D.W. Macmillan, and R.I.L. Guthrie, editors, TMS/CIM, series 257, No. 2, 1986, pp.
125139.
- G.J. Kipouros and D.R.
Sadoway, "Phase Diagram Studies of the Systems, KCl-K3MoCl6 and LiCl-K3MoCl6," Metall. Trans., B, 17B,
231, 1986.
- M.C. Flemings and D.R.
Sadoway, "Approaches to an Integrated Undergraduate Education in
Materials Science and Engineering," Frontiers in Materials
Education, Mat. Res. Soc. Symp. Proc., Vol. 66, L.W. Hobbs and G.L.
Liedl, editors, Pittsburgh PA, 1986, pp. 3-11.
- A.D. McLeod, J.M. Lihrmann, J.S.
Haggerty, and D.R. Sadoway, "Selection and Testing of Inert Anode
Materials for Hall Cells," Light Metals 1987, R.D. Zabreznik,
editor, TMS/AIME, Warrendale PA, 1987,
pp. 357-365.
- S.Y. Yoon and D.R. Sadoway,
"Spectroelectrochemical Study of Magnesium Electrolysis," in Light
Metals 1987, R.D. Zabreznik, editor, TMS/AIME,
Warrendale PA, 1987, pp. 851-859.
- L.H. Ng and D.R. Sadoway,
"Phase Separation Kinetics in Immiscible Liquids," Materials
Processing in the Reduced Gravity Environment of Space, Materials Research
Society Symposium, Vol. 87, R.H. Doremus and P.C. Nordine, editors,
Pittsburgh PA, 1987, pp. 281-283.
- J.K. Koziol and D.R. Sadoway,
"The Use of Molten Salts as Physical Models for the Study of
Solidification in Metals and Semiconductors," Materials Processing
in the Reduced Gravity Environment of Space, Materials Research Society
Symposium, Volume 87, R.H. Doremus and P.C. Nordine, editors,
Pittsburgh, PA, 1987, pp. 173-181.
- D.R. Sadoway, "Fused
Salt Electroplating," Electrodeposition Technology, Theory and
Practice," Proc. Vol. 87, L.T. Romankiw and D.R. Turner,
editors, The Electrochemical Society,
Pennington NJ, 1987, pp. 397-413.
- G.J. Kipouros and D.R.
Sadoway, "The Chemistry and Electrochemistry of Magnesium
Production," Advances in Molten Salt Chemistry, Vol. 6, G.
Mamantov, C.B. Mamantov and J. Braunstein, editors, Elsevier, Amsterdam, 1987, pp. 127-209.
- D.R. Sadoway, "Raman
Spectroscopic Studies of Fused Salt Electrolysis," Proc. 31st
Internat. Cong. Pure and Appl. Chem., Section 7, Phys. Chem., Sofia,
Bulgaria, 1987, pp. 172-179.
- S.Y. Yoon and D.R. Sadoway, "Spectroscopic and Electrochemical Studies of Molten Salt
Electrolysis of Aluminum and Magnesium," Proceedings of the Joint
International Symposium on Molten Salts, G. Mamantov et al., editors, The Electrochemical Society, Proc.
Vol. 87, Pennington NJ, 1987, pp. 1011-1017.
- C.S. Ritter and D.R. Sadoway,
"A Thermochemical Study of the Behavior of Impurities in the
Magnetherm Process," Light Metals 1988, L.G. Boxall, editor, TMS/AIME, Warrendale PA, 1987, pp. 799-805.
- F.W. Poulsen, N.H. Andersen,
K. Clausen, D.R. Sadoway and L.H. Øÿgendal, "Super Ionic Conduction
in Alkali Metal Hexachloro Niobates and Tantalates," Solid State
Ionics, 88, 271-275 (1988).
- J.F. Bredt and D.R. Sadoway,
"Cyclic Voltammetry in Liquid Hydrogen Chloride," Electrochemical
Technology in Electronics, L.T. Romankiw and T. Osaka, editors, The Electrochemical Society, Proc.
Vol. 88, Pennington NJ, 1988, pp. 361-372.
- R.P. Singh and D.R. Sadoway,
"Nonelectrolytic Deposition of Metals from Fused Salts," Electrochemical
Technology in Electronics, L.T. Romankiw and T. Osaka, editors, The Electrochemical Society, Proc.
Vol. 88, Pennington NJ, 1988, pp. 373-374.
- G.J. Kipouros and D.R.
Sadoway, "The Electrodeposition of Improved Molybdenum Coatings from
Molten Salts by the Use of Electrolyte Additives," J. Appl. Electrochem.,
18, 823-830, 1988.
- L.H. Ng and D.R. Sadoway,
"Density Measurements in the Succinonitrile-Water System," Can.
J. Chem., 66, 2428-2430, 1988.
- D.R. Sadoway, "Fused
Salt Electrolysis of Rare Earth Metals," Rare Earths, R.G.
Bautista and M.M. Wong, editors, TMS,
Warrendale PA, 1988, pp. 345-353.
- E.E. Shawki, S.N. Flengas and
D.R. Sadoway, "Drop Calorimetry Measurements of the Compounds RbNbCl6, CsNbCl6, KTaCl6,
and CsTaCl6," Can.
J. Chem., 67, 1193-1199, 1989.
- D.R. Sadoway, "Fused
Salt Electrolysis of Refractory Metals," Refractory Metals: State
of the Art 1988, P. Kumar and R.L. Ammon, editors, TMS, Warrendale PA, 1989, pp. 155-165.
- D.R. Sadoway,
"Challenges and Opportunities for Nonaqueous Electrochemistry,"
editorial commentary, Molten Salts Bulletin, Sels Fondus, No. 40,
1989, pp. 37.
- D.R. Sadoway, "A
Materials Systems Approach to Selection and Testing of Nonconsumable
Anodes for the Hall Cell," Light Metals 1990, C.A. Bickert,
editor, TMS, Warrendale PA, 1990, pp.
403-407.
- K. Kim and D.R. Sadoway,
"Electrical Conductivity Measurements of Molten Alkaline-Earth
Fluorides," Molten Salts, Proc. Seventh Internat. Symp., PV 90-17,
C.A. Hussey, ed., The
Electrochemical Society, Pennington NJ, 1990, pp. 174-178.
- D.R. Sadoway, "The
Synthesis of Refractory-Metal Compounds by Electrochemical Processing in
Nonaqueous Media," Refractory Metals: Extraction, Processing and
Applications, K.C. Liddell, D.R. Sadoway and R.G. Bautista, editors, TMS, Warrendale PA, 1990, pp. 213-220.
- D.R. Sadoway, "Metallurgical
Electrochemistry in Nonaqueous Media," Proceedings of the Elliott
Symposium on Chemical Process Metallurgy, P.J. Koros and G.R. St.
Pierre, editors, ISS, Warrendale PA,
1991, pp. 189-196.
- D.R. Sadoway, "The
Generation of Coatings and Thin Films of Refractory Metals by Electrolysis
in Nonaqueous Media," Tungsten and Tungsten Alloys - Recent
Advances, A. Crowson and E.S. Chen, editors, TMS, Warrendale PA, 1991, pp. 225-230.
- D.R. Sadoway,
"Metallurgical Electrochemistry: the Interface between Materials
Science and Molten Salt Chemistry," Molten Salt Chemistry and
Technology, M. Chemla and D. Devilliers, editors, Mat. Sci. Forum,
73-75, Trans Tech Publications Ltd., Zurich, 1991, pp. 555-560.
- D.R. Sadoway,
"Electrochemical Processing of Refractory Metals," Journal of
Metals, 43 (7), 15-19 (1991).
- K.B. Kim and D.R. Sadoway,
"Electrical Conductivity Measurements of Molten Alkaline-earth
Fluorides," J. Electrochem. Soc., 139, 1027-1033
(1992).
- D.R. Sadoway, "Treatment
of Chromate Residue by Direct Electrolysis in Molten Oxides," Residues
and Effluents, Processing and Environmental Considerations, R.G.
Reddy, W.P. Imrie, and P.B. Queneau, editors, TMS,
Warrendale PA, 1992, pp. 469-473.
- K.B. Kim and D.R. Sadoway,
"Electrical Conductivity Measurements of Binary Solutions of Molten
Alkaline-earth Fluorides," J. Electrochem. Soc., 139
(8), 2132-2137 (1992).
- J.N. Hryn and D.R. Sadoway,
"Cell Testing of Metal Anodes for Aluminum Electrolysis," Light
Metals 1993, S.K. Das, editor, TMS,
Warrendale PA, 1993, pp. 475-483.
- D.R. Sadoway, "Synthesis
of Advanced Materials by Electrochemical Processing in Nonaqueous
Media," in New Trends and Approaches in Electrochemical Technology,
N. Masuko, T. Osaka, and Y. Fukunaka, editors, Kodansha Ltd., Tokyo, 1993,
pp. 65-74.
- D.R. Sadoway, M.F. Rubner,
and M.C. Flemings, "MIT's New Materials Synthesis and Processing
Laboratory: a Vehicle for Incorporating Design into the Undergraduate
Curriculum," in Design Education in Metallurgical and Materials
Engineering, M.E. Schlesinger and D.E. Mikkola, editors, TMS, Warrendale, PA, 1993, pp. 93-101.
- N.A. Fried, S.L.
Schiefelbein, K.G. Rhoads, and D.R. Sadoway, "A New Technique for
Electrical Conductivity Measurements in Molten Salts," in Proc.
Internat. Symp. on Molten Salt Chem. and Technol. - 1993, PV 93-9,
M.-L. Saboungi and H. Kojima, editors, The Electrochemical Society,
Pennington, NJ, 1993, pp. 296-305.
- J. Hisamoto and D.R. Sadoway,
"A Study of the Mechanism of Selenium Electrodeposition from Liquid
Hydrogen Chloride," in Proceedings of the Second International
Symposium on Electrochemical Processing of Tailored Materials, PV 93-12,
R.A. Alkire, N. Masuko, Y. Ito, D.R. Sadoway, and D.J. Economou, editors,
The Electrochemical Society, Pennington, NJ, 1993, pp. 108-116.
- D.R. Sadoway, "New
Opportunities for Waste Treatment by Electrochemical Processing in Molten
Salts," in Metals and Materials Waste Reduction, Recovery and
Remediation, K.C. Liddell, R.G. Bautista, and R.J. Orth, editors, TMS, Warrendale, PA, 1994, pp. 73-76.
- D.R. Sadoway, "New
Opportunities for Metals Extraction and Waste Treatment by Electrochemical
Processing in Molten Salts," J. Mater. Res., 10,
487-492 (1995).
- D.R. Sadoway, “Electrochemical
Processing in Nonaqueous Media,” in Proceedings of the International
Harald A. Øye Symposium, M. Sørlie, T. Østvold, and R. Huglen, editors,
University of Trondheim, Trondheim, 1995, pp. 299-312.
- R. de Neufville, S.R.
Connors, F.R. Field, III, D. Marks, D.R. Sadoway, and R.D. Tabors,
"The Electric Car Unplugged," Technology Review, 99,
30-36 (1996).
- T.H. Okabe, T.N. Deura, T.
Oishi, K. Ono, and D.R. Sadoway, "Electrochemical Deoxidation of Yttrium-Oxygen
Solid Solutions," J. Alloys Comp., 237, 150-154 (1996).
- H.B. Shapiro and D.R.
Sadoway, "Densities in the Liquid Hydrogen Chloride Solvent
System," J. Phys. Chem., 100 (14), 5956-5963 (1996).
- T.H. Okabe, T.N. Deura, T.
Oishi, K. Ono, and D.R. Sadoway, "Thermodynamic Properties of Oxygen
in Yttrium-Oxygen Solid Solutions," Metall. Materials Trans. B,
27B, 839-845 (1996).
- R.B. Michnick and D.R.
Sadoway, "Phase Diagram of Butyronitrile-Chloroethane Determined by
Differential Thermal Analysis," J. Phys. Chem., 100,
19628-19631 (1996).
- S.S. Nissen and D.R. Sadoway,
"Perfluorocarbon (PFC) Generation in Laboratory-Scale Aluminum
Reduction Cells," Light Metals 1997, R. Huglen, editor, TMS, Warrendale, PA, 1997, pp. 159-164.
- R.B. Michnick, K.G. Rhoads,
and D.R. Sadoway, "Relative Dielectric Constant Measurements in the
Butyronitrile-Chloroethane System at Subambient Temperatures," J.
Electrochem. Soc., 144, 2392-2398 (1997).
- S.L. Schiefelbein and D.R.
Sadoway, "A High-accuracy, Calibration-free
Technique for Measuring the Electrical Conductivity of Molten Oxides,"
Metall. Materials Trans. B, 28 B, 1141-1149 (1997).
- Y-M. Chiang, Y-I. Jang, H.
Wang, B. Huang, D.R. Sadoway, and P. Ye, "Synthesis of LiCoO2 by Decomposition and Intercalation
of Hydroxides," J. Electrochem. Soc., 145, 887-891
(1998).
- G. Ceder, Y-M. Chiang, D.R.
Sadoway, M.K. Aydinol, Y-I. Jang, and B. Huang, "Identification
of cathode materials for lithium batteries guided by first-principles
calculations," Nature, 392, 694-696 (1998).
- D.R. Sadoway, "Advances
and Innovations in the Extraction of Aluminum and Magnesium,"
Molten Salt Chemistry and Technology 5, Proceedings of the 5th
International Symposium on Molten Salt Chemistry and Technology, Dresden,
Germany, August 1997, ed. H. Wendt, Molten Salt Forum Vols. 5-6, Trans
Tech Publications, Zurich, 1998, pp. 43-48.
- G.J. Kipouros and D.R.
Sadoway, "Toward New Technologies for the Production
of Lithium," JOM, 50 (5) 24-26 (1998).
- Y-I. Jang, B. Huang, Y-M.
Chiang, and D.R. Sadoway, "Stabilization of LiMnO2 in the a-NaFeO2
Structure Type by LiAlO2
Addition," Electrochemical and Solid-State Letters, 1
(1), 13-16 (1998).
- S.L. Schiefelbein, N.A.
Fried, K.G. Rhoads, and D.R. Sadoway, "A high-accuracy, calibration-free
technique for measuring the electrical conductivity of liquids," Rev.
Sci. Instrum., 69 (9), 3308-3313 (1998).
- B. Huang, Y-I. Jang, Y-M.
Chiang, and D.R. Sadoway, "Electrochemical
Evaluation of LiCoO2
Synthesized by Decomposition and Intercalation of Hydroxides for
Lithium-ion Battery Applications," J. Appl. Electrochem.,
28 (12), 1365-1369 (1998).
- T.H. Okabe and D.R. Sadoway,
"Metallothermic Reduction as an Electronically
Mediated Reaction," J. Mater. Res., 13 (12),
3372-3377 (1998).
- P.P. Soo, B. Huang, Y-I.
Jang, Y-M. Chiang, D.R. Sadoway, and A.M. Mayes, "Rubbery
Block Copolymer Electrolytes for Solid-state Rechargeable Batteries,"
J. Electrochem. Soc., 146 (1), 32-37 (1999).
- T.H. Okabe, H. Zhu, and D.R.
Sadoway, "Materials Synthesis by Metallothermic Reduction," in Proceedings
of the International Terje Østvold Symposium, H.A. Øye and O. Wærnes,
editors, The Norwegian University of Science and Technology, Trondheim,
1998, pp. 77-88.
- Y.-M. Chiang, D.R. Sadoway,
Y.-I. Jang, B. Huang, and H. Wang, "High Capacity,
Temperature-Stable Lithium Aluminum Manganese Oxide Cathodes for
Rechargeable Batteries," Electrochem. Solid-State Lett., 2
(3), 107-110 (1999).
- Y.-I. Jang, B. Huang, H.
Wang, D.R. Sadoway, G. Ceder, Y.-M. Chiang, H. Liu, and H. Tamura, "LiAlyCo1-yO2
Intercalation Cathode for Rechargeable Lithium Batteries," J.
Electrochem. Soc., 146 (3), 862-868 (1999).
- H. Wang, Y.-I. Jang, B.
Huang, D.R. Sadoway, and Y.-M. Chiang, "TEM Study of
Electrochemical Cycling Induced Damage and Disorder in LiCoO2 Cathodes for Rechargeable Batteries,"
J. Electrochem. Soc., 146 (2), 473-480 (1999).
- H. Zhu and D.R. Sadoway,
"The Electrode Kinetics of Perfluorocarbon (PFC) Generation," Light
Metals 1999, C.E. Eckert, editor, TMS,
Warrendale, PA, 1999, pp. 241-246.
- H. Wang, Y.-I. Jang, B.
Huang, Y.-M. Chiang, and D.R. Sadoway, "Electron
Microscopic Characterization of Electrochemically Cycled LiCoO2 and Li(Al,Co)O2 Battery Cathodes," J.
Power Sources, 81-82, 594-598 (1999).
- Y.-I. Jang, B. Huang, H.
Wang, G.R. Maskaly, G. Ceder, D.R. Sadoway, and Y.-M. Chiang, "Synthesis and Characterization of LiAlyCo1-yO2 and LiAlyNi1-yO2," J. Power Sources, 81-82,
589-593 (1999).
- D.R. Sadoway, "Materials
Science as a Vehicle for Teaching Mainstream Chemistry," J. Mater.
Ed., 21 (1 & 2), 5-10 (1999).
- Y.-I. Jang, B. Huang, H.
Wang, D.R. Sadoway, Y.-M. Chiang, "Electrochemical
Cycling-Induced Spinel Formation in High-Charge-Capacity Orthorhombic
LiMnO2," J.
Electrochem. Soc., 146 (9), 3217-3223 (1999).
- H. Zhu and D.R. Sadoway, “An
Electroanalytical Study of Electrode Reactions on Carbon Anodes During
Electrolytic Production of Aluminum,” Light Metals 2000, R.D.
Peterson, editor, TMS, Warrendale, PA, 2000, pp. 257-263.
- Donald L. Anglin, Donald R.
Sadoway, Battery, in AccessScience@McGraw-Hill, http://www.accessscience.com/server-java/Arknoid/science/AS/Encyclopedia/0/07/Est_075200_frameset.html
, last modified: July 24, 2002.
- Y.-I. Jang, B. Huang, F.C.
Chou, D.R. Sadoway, and Y.-M. Chiang, “Magnetic characterization of l-MnO2 and Li2Mn2O4 prepared by electrochemical cycling
of LiMn2O4,” J. Appl. Phys., 87
(10), 7382-7388 (2000).
- H. Zhu and D.R. Sadoway, “Towards
Elimination of Anode Effect and PFC Emissions via Current Shunting,” Light
Metals 2001, J.L. Anjier, editor, TMS, Warrendale, PA, 2001, pp.
303-307.
- D.R. Sadoway, “Inert Anodes for the Hall-Héroult Cell: The Ultimate
Materials Challenge,” JOM, 53 (5), 34-35 (2001).
- D.R. Sadoway, A.M. Mayes, B.
Huang, S. Mui, P.P. Soo, D.H. Staelin, and C.C. Cook, “High
Energy Density, Thin-Film, Rechargeable Lithium Batteries for Marine Field
Operations,” J. Power Sources, 97-98, 674-676 (2001).
- D.R. Sadoway, A.M. Mayes, B.
Huang, P.E. Trapa, P.P. Soo, and P. Bannerjee, “Self-doped
Block Copolymer Electrolytes for Solid-State, Rechargeable Lithium
Batteries,” J. Power Sources, 97-98, 621-623 (2001).
- A.G. Ruzette, P.P. Soo, D.R.
Sadoway, and A.M. Mayes, “Melt-Formable Block Copolymer
Electrolytes for Lithium Rechargeable Batteries,” J. Electrochem.
Soc., 148 (6), A537-A543 (2001).
- N.A. Fried, K.G. Rhoads, and
D.R. Sadoway, "Transference Number Measurements of
TiO2 - BaO Melts by
Stepped-Potential Chronoamperometry," Electrochim. Acta, 46
(22), 3351-3358 (2001).
- H. Zhu and D.R. Sadoway,
"Synthesis of Nanoscale Particles of Ta and Nb3Al by Homogeneous Reduction in
Liquid Ammonia," J. Mater. Res.,16 (9), 2544-2549
(2001).
- G.J. Kipouros and D.R.
Sadoway, "A Thermochemical Analysis of the
Production of Anhydrous MgCl2,"
J. Light Met., 1 (2), 111-117 (2001).
- P.E. Trapa, B. Huang, D.R.
Sadoway, and A.M. Mayes, "Block Copolymer
Electrolytes Synthesized by Atom Transfer Radical Polymerization (ATRP)
for Solid-State, Thin-Film Lithium Batteries," Electrochem.
Solid-State Lett., 5 (5) A85-A88 (2002).
- S.C. Mui, P.E. Trapa, B.
Huang, P.P. Soo, M.I. Lozow, T.C. Wang, R.E. Cohen, A.N. Mansour, S.
Mukerjee, A.M. Mayes, and D.R. Sadoway, “Block
Copolymer-Templated Nanocomposite Electrodes for Rechargeable Lithium
Batteries,” J. Electrochem. Soc., 149 (12), A1610-A1615
(2002).
- D.J. Harris, T.J. Bonagamba,
K. Schmidt-Rohr, P.P. Soo, D.R. Sadoway, and A.M. Mayes, “Solid-State NMR Investigation of Block Copolymer Electrolyte
Dynamics,” Macromolecules,
35 (9), 3772-3774 (2002).
- A.C. Ducret, D. Khetpal, and
D.R. Sadoway “Electrical Conductivity and
Transference Number Measurements of FeO - CaO - MgO - SiO2 Melts,” Molten Salts, Proc.
Thirteenth Internat. Symp., H.C. Delong, R.W. Bradshaw, M. Matsunaga, G.R.
Stafford, and P.C. Trulove, eds., The Electrochemical Society, Pennington
NJ, 2002, pp. 347-353.
- H. Zhu and D.R. Sadoway,
“Towards Elimination of the Anode Effect and
Perfluorocarbon Emissions from Hall-Héroult Cells,” Molten
Salts, Proc. Thirteenth Internat. Symp., H.C. Delong, R.W. Bradshaw, M.
Matsunaga, G.R. Stafford, and P.C. Trulove, eds., The Electrochemical
Society, Pennington NJ, 2002, pp. 411-418.
- D.R. Sadoway and A.M. Mayes, “Portable Power: Advanced Rechargeable Lithium
Batteries,” MRS Bulletin, 27 (8),
590-594 (2002).
- Y.-I. Jang, F.C. Chou, B.
Huang, D.R. Sadoway, and Y.-M. Chiang, “Magnetic
characterization of orthorhombic LiMnO2
and electrochemically transformed spinel LixMnO2 (x<1)," J. Phys. Chem.
Solids, 64 (12), 2525-2533 (2003).
- D.R. Sadoway, “Block and graft copolymer electrolytes for
high-performance, solid-state, lithium batteries," J. Power
Resources, 129 (1), 1-3 (2004).
- L.M. Bartolo, S.C. Glotzer,
J.I. Khan, A.C. Powell, IV, D.R. Sadoway, and K.M. Anderson, “MatDL.org:
The Materials Digital Library and the National Science Digital Library
Program,” J. Mater. Ed . 26 (3-4), 213-218
(2004).
- Patrick E. Trapa, You-Yeon
Won, Simon C. Mui, Elsa Olivetti, Biying Yuang, D. R. Sadoway, Anne M.
Mayes, and Steven Dallek, “Rubbery Graft Copolymer
Electrolytes for Solid-State, Thin-Film Lithium Batteries," J.
Electrochem. Soc., 152 (1), A1-A5 (2005).
- Sang-Woog Ryu, Patrick E.
Trapa, Solar C. Olugebefola, Juan A. Gonzalez-Leon, D. R. Sadoway, and
Anne M. Mayes, “Effect of Counter Ion Placement on
Conductivity in Single-Ion Conducting Block Copolymer Electrolytes,"
J. Electrochem. Soc., 152 (1), A158-A163
(2005).
- A.M. Johnson, D.R. Sadoway,
M.J. Cima, and R. Langer, "Design and Testing of an
Impedance-Based Sensor for Monitoring Drug Delivery," J.
Electrochem. Soc., 152 (1), H6-H11 (2005).
- L.M. Bartolo, C.S. Lowe, D.R.
Sadoway, A.C. Powell, IV, and S.C. Glotzer, “NSDL MatDL: Exploring digital
library roles,” D-Lib Magazine, 11 (3), (2005).
- M. Kurian, M.E. Galvin, P.E.
Trapa, D.R. Sadoway, and A.M. Mayes, “Single-ion
conducting polymer-silicate nanocomposite electrolytes for lithium battery
applications,” Electrochim. Acta, 50 (10), 2125-2134 (2005).
- L. Bartolo, C. Lowe, D.R.
Sadoway, and P.E. Trapa, “Large introductory science
courses & digital libraries,” in Proceedings of the 5th
ACM/IEEE-CS joint conference on Digital libraries , ACM, New York,
NY, p. 366.
- N. Ariel, G. Ceder, D. R.
Sadoway, and E.A. Fitzgerald, “Electrochemically
Controlled Transport of Lithium through Ultra-thin SiO2 ,” J. Appl. Phys., 98
, 023516 (2005).
- P.E. Trapa, M.H. Acar, D.R.
Sadoway, and A.M. Mayes, “Synthesis and Characterization
of Single-ion Graft Copolymer Electrolytes,” J. Electrochem. Soc.,
152 (12), A2281-A2284 (2005).
- L.M. Bartolo, S.C. Glotzer,
C.S. Lowe, A.C. Powell, IV, D.R. Sadoway, J.A. Warren, V.K. Tewary, and K.
Rajan, “NSF NSDL Materials Digital Library & MSE education,” J. Mater. Ed., 28 (1),
21-26 (2006).
- P.E. Trapa, A.B. Reyes, R.S.
Das Gupta, A.M. Mayes, and D.R. Sadoway, “Polarization
in Cells Containing Single-ion Graft Copolymer Electrolytes,” J.
Electrochem. Soc., 153 (6), A1098-A1101 (2006).
- S.C. Mui, J. Jasinski, V.J. Leppert,
M. Mitome, D.R. Sadoway, and A.M. Mayes, “Microstructure Effects on the
Electrochemical Kinetics of Vanadium Pentoxide Thin-film Cathodes,” J.
Electrochem. Soc., 153 (7), A1372-A1377 (2006).
- E.A. Olivetti, J.H. Kim, D.R.
Sadoway, A. Asatekin, and A.M. Mayes, “Sol-gel Synthesis of Vanadium Oxide
within a Block Copolymer Matrix,” Chem. Mater.; (Article); 2006; 18 (12), 2828-2833. DOI: 10.1021/cm060119s
- J.L. Lutkenhaus, E.A. Olivetti, E.A. Verploegen, B.M. Cord, D.R. Sadoway, and P.T. Hammond, “Anisotropic Structure and Transport in Self-Assembled Layered Polymer-Clay Nanocomposites,” Langmuir , 23 (16), 8515-8521 (2007).
- A.H.C. Sirk and D.R. Sadoway, “Electrochemical Synthesis of Diamondlike Carbon Films,” J. Electrochem. Soc ., 155 (5), E49-E55 (2008).
Return to Prof. Sadoway's home page
Sadoway curriculum vitae maintained by Hilary Sheldon (comments to
hsheldon@mit.edu). Last modified 22 April 2008.