radosevich group - publications

Deoxyfluorination of 1°, 2°, and 3° Alcohols by Nonbasic O–H Activation and Lewis Acid-Catalyzed Fluoride Shuttling

Hye Won Moon, Marissa N. Lavagnino, Soohyun Lim, Maximilian D. Palkowitz, Michael D. Mandler, Gregory L. Beutner, Myles J. Drance, Jeffrey M. Lipshultz, Paul M. Scola, and Alexander T. Radosevich

J. Am. Chem. Soc. 2023, 145, 22735–22744.

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Tandem C/N-Difunctionalization of Nitroarenes: Reductive Amination and Annulation by a Ring Expansion/Contraction Sequence

Gen Li, Marissa N. Lavagnino, Siraj Z. Ali, Shicheng Hu, and Alexander T. Radosevich

J. Am. Chem. Soc. 2023, 145, 41–46.

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Metal–Ligand Role Reversal: Hydride Transfer Catalysis by a Functional Phosphorus Ligand with a Spectator Metal

Quinton J. Bruch, Akira Tanushi, Peter Müller, and Alexander T. Radosevich

J. Am. Chem. Soc. 2022, 144, 21443–21447.

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Two-Site O–H Addition to an Iridium Complex Featuring a Nonspectator Tricoordinate Phosphorus Ligand

Myles J. Drance, Akira Tanushi, and Alexander T. Radosevich

J. Am. Chem. Soc. 2022, 144, 20243–20248.

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Chemoselective Primary Amination of Aryl Boronic Acids by P^III/P^V=O-Catalysis: Synthetic Capture of the Transient Nef Intermediate HNO

Seung Youn Hong and Alexander T. Radosevich

J. Am. Chem. Soc. 2022, 144, 8902–8907.

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Enabling Reductive C–N Cross-Coupling of Nitroalkanes and Boronic Acids by Steric Design of P(III)/P(V)=O Catalysts

Gen Li, Yuzuru Kanda, Seung Youn Hong, and Alexander T. Radosevich

J. Am. Chem. Soc. 2022, 144, 8242–8248.

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Uniting Amide Synthesis and Activation by P^III/P^V-Catalyzed Serial Condensation: Three-Component Assembly of 2-Amidopyridines

Jeffrey M. Lipshultz and Alexander T. Radosevich

J. Am. Chem. Soc. 2021, 143, 14487–14494.

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P^III/P^V=O-Catalyzed Intermolecular N–N Bond Formation: Cross-Selective Reductive Coupling of Nitroarenes and Anilines

Gen Li, Steven P. Miller, and Alexander T. Radosevich

J. Am. Chem. Soc. 2021, 143, 14464–14469.

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Main Group Redox Catalysis of Organopnictogens: Vertical Periodic Trends and Emerging Opportunities in Group 15

Jeffrey M. Lipshultz, Gen Li, and Alexander T. Radosevich

J. Am. Chem. Soc. 2021, 143, 1699–1721.

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Organophosphorus-Catalyzed Relay Oxidation of H–Bpin: Electrophilic C–H Borylation of Heteroarenes

Jeffrey M. Lipshultz, Yue Fu, Peng Liu, and Alexander T. Radosevich

Chem. Sci. 2021, 12, 1031–1037.

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Reductive C_sp2–N Coupling by P^III/P^V=O–Catalysis

Gen Li, Colet te Grotenhuis, and Alexander T. Radosevich

Trends Chem. 2021, 3, 72–73.

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Ancillary Tethering Influences σ³-P vs σ⁵-P Speciation and Enables Intermolecular S–H Oxidative Addition to Nontrigonal Phosphorus Compounds

Hye Won Moon, Ayan Maity, and Alexander T. Radosevich

Organometallics 2021, 40, 2785–2791.

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Enthalpy-Controlled Insertion of a “Nonspectator” Tricoordinate Phosphorus Ligand into Group 10 Transition Metal–Carbon Bonds

Seung Jun Hwang, Akira Tanushi, and Alexander T. Radosevich

J. Am. Chem. Soc. 2020, 142, 21285–21291.

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P(III)/P(V)-Catalyzed Methylamination of Arylboronic Acids and Esters: Reductive C−N Coupling with Nitromethane as a Methylamine Surrogate

Gen Li, Ziyang Qin, and Alexander T. Radosevich

J. Am. Chem. Soc. 2020, 142, 16205–16210.

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Round-Trip Oxidative Addition, Ligand Metathesis, and Reductive Elimination in a P^III/P^V Synthetic Cycle

Soohyun Lim and Alexander T. Radosevich

J. Am. Chem. Soc. 2020, 142, 16188–16193.

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Using Nature’s Blueprint to Expand Catalysis with Earth-Abundant Metals

R. Morris Bullock, Jingguang G. Chen, Laura Gagliardi, Paul J. Chirik, Omar K. Farha, Christopher H. Hendon, Christopher W. Jones, John A. Keith, Jerzy Klosin, Shelley D. Minteer, Robert H. Morris, Alexander T. Radosevich, Thomas B. Rauchfuss, Neil A. Strotman, Aleksandra Vojvodic, Thomas R. Ward, Jenny Y. Yang, and Yogesh Surendranath

Science 2020, 369, eabc3183.

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Addition Reactions of a Phosphorus Triamide to Nitrosoarenes and Acylpyridines

Colet te Grotenhuis, Jared T. Mattos, and Alexander T. Radosevich

Phosphorus Sulfur Silicon Relat. Elem. 2020, 195, 940–946.

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An Improved P^III/P^V=O-Catalyzed Reductive C–N Coupling of Nitroaromatics and Boronic Acids by Mechanistic Differentiation of Rate- and Product-Determining Steps

Gen Li, Trevor V. Nykaza, Julian C. Cooper, Antonio Ramirez, Michael R. Luzung, and Alexander T. Radosevich

J. Am. Chem. Soc. 2020, 142, 6786–6799.

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P^III/P^V=O-Catalyzed Cascade Synthesis of N-Functionalized Azaheterocycles

Trevor V. Nykaza, Gen Li, Junyu Yang, Michael R. Luzung, and Alexander T. Radosevich

Angew. Chem. Int. Ed. 2020, 59, 4505–4510.

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anti-1,2,2,3,4,4-Hexamethylphosphetane 1-Oxide

Trevor V. Nykaza, Julian C. Cooper, and Alexander T. Radosevich

Org. Synth. 2019, 96, 418–435.

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A Nontrigonal Tricoordinate Phosphorus Ligand Exhibiting Reversible ‘Nonspectator’ L/X–Switching

Gregory T. Cleveland and Alexander T. Radosevich

Angew. Chem. Int. Ed. 2019, 58, 15005–15009.

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Driving Recursive Dehydration by P^III/P^V Catalysis: Annulation of Amines and Carboxylic Acids by Sequential C–N and C–C Bond Formation

Morgan Lecomte, Jeffrey M. Lipshultz, Shin-Ho Kim-Lee, Gen Li, and Alexander T. Radosevich

J. Am. Chem. Soc. 2019, 141, 12507–12512.

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Tetragonal Phosphorus(V) Cations As Tunable and Robust Catalytic Lewis Acids

James C. Gilhula and Alexander T. Radosevich

Chem. Sci. 2019. 10, 7177–7182.
[Selected as part of the 2019 Chemical Science HOT Article Collection]

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PEt₃-Mediated Deoxygenative C–N Coupling of Nitroarenes and Boronic Acids

Trevor V. Nykaza, Junyu Yang, and Alexander T. Radosevich

Tetrahedron 2019, 75, 3248–3252.
[Invited contribution to special issue in honor of Ryan Shenvi's Tetrahedron Young Investigator Award]

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Validating the Biphilic Hypothesis of Nontrigonal P(III) Compounds

Kyounghoon Lee, Anastasia Blake, Akira Tanushi, Sean McCarthy, Daniel Kim, Sydney Loria, Courtney Donahue, Kyle Spielvogel, Jason Keith, Scott Daly, and Alexander T. Radosevich

Angew. Chem. Int. Ed. 2019, 58, 6993–6998.

abstract | pdf | supplemental information