A Phosphetane Catalyzes Deoxygenative Condensation of α-Keto Esters and Carboxylic Acids via P(III)/P(V)=O Redox Cycling

Wei Zhao, Patrick K. Yan, and Alexander T. Radosevich

J. Am. Chem. Soc. 2015137, 616–619.

abstract  |  pdf  |  supplemental information


Phosphorus(III)-Mediated Reductive Condensation of α-Keto Esters and Protic Pronucleophiles

Wei Zhao and Alexander T. Radosevich

Org. Synth. 201592, 267–276.

abstract  |  pdf 


Reversible Intermolecular E–H Oxidative Addition to Geometrically Deformed and Structurally Dynamic Phosphorous Triamide

Wei Zhao, Sean M. McCarthy, Ting Yi Lai, Hemant P. Yennawar, and Alexander T. Radosevich

J. Am. Chem. Soc. 2014136, 17634–17644.

abstract  |  pdf  |  supplemental information


A Phosphine-Mediated Stereocontrolled Synthesis of Z-Enediynes by a Vicinal Dialkynylation of Ethynylphosphonium Salts

Kyle D. Reichl and Alexander T. Radosevich

Chem. Comm. 201450, 9302–9305.

abstract  |  pdf  |  supplemental information


Intermolecular N–H Oxidative Addition of Ammonia, Alkylamines, and Arylamines to a Planar σ3-Phosphorus Compound via an Entropy-Controlled Electrophilic Mechanism

Sean M. McCarthy, Yi-Chun Lin, Deepa Devarajan, Ji Woong Chang, Hemant P. Yennawar, Robert M. Rioux, Daniel H. Ess, and Alexander T. Radosevich

J. Am. Chem. Soc. 2014136, 4640–4650.

abstract  |  pdf  |  supplemental information


Catalyzing Pyramidal Inversion: Configurational Lability of P-Stereogenic Phosphines via Single Electron Oxidation

Kyle D. Reichl, Daniel H. Ess, and Alexander T. Radosevich

J. Am. Chem. Soc. 2013135, 9354–9357.

abstract  |  pdf  |  supplemental information


A Csp3Csp3 Bond Forming Reductive Condensation of α-Keto Esters and Enolizable Carbon Pronucleophiles

Wei Zhao, Darla M. Fink, Carolyn A. Labutta, and Alexander T. Radosevich

Org. Lett. 2013, 15, 3090–3093.

abstract  |  pdf  |  supplemental information


A Synthesis of α-Amino Acids via Direct Reductive Carboxylation of Imines with Carbon Dioxide

Ajay A. Sathe, Douglas Hartline, Alexander T. Radosevich

Chem. Commun. 201349, 5040–5042.

abstract  |  pdf  |  supplemental information


Reductive Homocondensation of Benzylidene- and Alkylidenepyruvate Esters by a P(NMe2)3-Mediated Tandem Reaction

Sunewang Rixin Wang , Alexander T. Radosevich

Org. Lett. 201315, 1926–1929.

abstract  |  pdf  |  supplemental information


A Nonmetal Approach to α-Heterofunctionalized Carbonyl Derivatives by Formal Reductive X–H Insertion

Eric Miller, Wei Zhao, Jonathan Herr, Alexander T. Radosevich

Angew. Chem. Int. Ed. 2012, 51, 10605–10609

abstract  |  pdf  |  supplemental information


Main Group Redox Catalysis: Reversible P(III)/P(V) Redox Cycling at a Phosphorus Platform

Nicole Dunn, Minji Ha, Alexander T. Radosevich

J. Am. Chem. Soc. 2012134, 11330–11333.

abstract | pdf | supplemental information