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Module: Rubber Processing in Ancient Mesoamerica
Coordinating instructor: Dorothy Hosler
Theme:
Ancient Mexican peoples harvested latex from Castilla elastica,
the indigenous rubber tree, and processed it using the juice of Ipomoea
alba, a species of morning glory vine, to produce rubber. Their discovery
of this rubber processing technology at 1600 BCE predated Charles Goodyear's
discovery of vulcanization by approximately 3500 years. Ancient Mexican
peoples used rubber principally as a ritual material, whereas the interests
of modern western society lay in industrial applications. Ancient Mexicans
made large, solid, heavy (7 kg) balls from rubber, which they used in
a sacred ball game that became a key ritual event throughout Mesoamerica,
from Olmec to Aztec times. They made solid and hollow rubber figurines
to represent deities. Rubber was also engineered for practical ends to
make sandals and to haft tools. This module explores the independent development
of rubber in two distinct social and cultural milieux and illustrates
the ways in which cultural variables can shape technologies.
Module program:
The module will be structured as lecture/discussion and laboratory sessions.
Lectures will address the social context of rubber processing in ancient
Mexico, in particular the Mesoamerican ritual ball game, and will contrast
ancient Mexican and western uses of rubber. The materials engineering
differences between the ancient and modern rubbers will be explored through
consideration of their polymer chemistries, their performance as elastomers,
and their response to property development. In laboratory, participants
will reproduce ancient Mesoamerican rubber using the two indigenous materials
(C. elastica and I. alba) and will test the mechanical properties
of both the Mexican product and modern industrial rubbers.
Material culture component:
Participants will examine the cultural environment in which rubber processing
developed in ancient Mexico through readings, lectures, and discussions
and will compare this to the development of rubber production in western
industrial society. We will consider and evaluate the historical evidence
for the ancient processing of rubber, the botanical evidence for processing,
and the ethnographic and archaeological data for processing. Discussions
will focus on the ways in which social forces shape technical choices,
principally in the products made from rubber (ritual rubber balls and
figurines vs. automobile tires, for example) and in rubber processing
technologies. In ancient Mexico the rubber ball game was a central event
that recapitulated the Mesoamerican creation story in which forces of
good challenged the forces of evil on a ball court. The victors, the forces
of good, became the moon and the sun, thus setting the universe into motion.
Thus rubber was a material intimately connected to the origins of society
in Mesoamerican cosmology and in the ritual games that expressed that
cosmology. Contemporary indigenous Mexican peoples continue to play versions
of the ancient ball game, and in the coastal plain of Chiapas local villagers
harvest latex and mix it with morning glory vine to form traditional products.
The western experience is entirely different. Goodyear's discovery made
the automobile possible and fueled industrialization. Multiple applications
of latex and rubber allowed advances in medicine (urinary catheters, latex
surgical gloves) and in other fields. Rubber in western society is relegated
nearly exclusively to utilitarian applications as well as to sports and
other non-sacred cultural activities.
Materials science/engineering and laboratory component:
Treatment of the mechanical behavior of polymeric materials will serve
as the basis for a full discussion of ancient and industrial rubbers.
Molecular weight, crystallinity, crosslinking, molecular orientation,
and physical entanglements are the primary characteristics of polymeric
structures that are important in determining the strength and overall
mechanical behavior of polymers. We will pay particular attention to elastomers,
which include natural and synthetic rubbers, as loosely chemically crosslinked,
amorphous polymer networks typically with a low glass transition temperature
below room temperature (Tg<RT). Elastomers exhibit non-linear deformation
and full recovery and can extend elastically for strains up to several
hundred percent. Comparison of Mesoamerican and industrial rubber processing
will consider (1) the curing of natural latex by crosslinking of polyisoprene
chains with sulfur (vulcanization), and (2) dissolution by I. alba
of proteins that surround polyisoprene chains in the latex emulsion of
C. elastica, enabling their entanglement, interaction, and stiffening
of the material, as well as crosslinking or cyclizing of the chains by
sulfonic acid and sulfonyl chloride moieties present in I. alba
(ancient Mexican processing).
The laboratory: Laboratory sessions will include the processing
of rubber and the mechanical testing of rubber made by different processing
techniques.
(1) Processing rubber: All participants will follow
the ancient Mexican processing regime to produce rubber. The latex and
morning glory vine components will be gathered in Chiapas, Mexico by
DMSE/SI graduate students. Participants will fashion "Mexican"
rubber into balls, figurines, and slabs for mechanical testing.
(2) Mechanical properties of rubber: Groups of participants
will carry out a range of mechanical tests and property determinations
of "Mexican" and industrial rubbers:
(a) measurement of the stress versus strain curve of
"Mexican" rubber in uniaxial tension in order to obtain a
value for the elastic modulus, the degree of strain hardening, the strain-to-failure,
energy of deformation (toughness), and the mechanical hysteresis;
(b) comparative tensile tests and determination of
percent elongation at break for samples of "Mexican" rubber,
vulcanized rubber, and carbon black-filled-natural rubber;
(c) determination of mechanical property (elasticity
and toughness) changes in "Mexican" rubber produced by varying
the volume fraction of I. alba to C. elastica (tailoring
rubber properties to rubber use, e.g. rubber balls vs. rubber hafting).
If time allows, SI participants, faculty, and graduate students will
assemble on the MIT playing field to play the Mexican ball game with the
rubber balls made in the laboratory!
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