(29) Synthesis and Electrical Properties of Covalent Organic Frameworks with Heavy Chalcogens - pdf
Duhovic, S.; Dincă, M.
Chem. Mater. 2015, 27, in press.

 

Dynamic DMF binding in MOF-5 enables the formation of metastable cobalt-substituted MOF-5 analogs

 

(28) Dynamic DMF binding in MOF-5 enables the formation of metastable cobalt-substituted MOF-5 analogs - pdf
Brozek, C. K.; Michaelis, V. K.; Ong, T.-C.; Bellarosa, L.; Lopez, N.; Griffin, R. G.; Dincă, M.
ACS Central Science 2015, 1, in press.

 

Dynamic DMF binding in MOF-5 enables the formation of metastable cobalt-substituted MOF-5 analogs

 

(27) Thermodynamic parameters of cation exchange in MOF-5 and MFU-4l - pdf
Brozek, C. K.; Dincă, M.
Chem. Commun. 2015, 51, 11780-11782.

 

Thermodynamic parameters of cation exchange in MOFs

 

(26) NO Disproportionation at a Mononuclear Site-isolated Fe(II) Center in Fe(II)-MOF-5 - pdf
Brozek, C. K.; Miller, J. T.; Stoian, S. A.; Dincă, M.
J. Am. Chem. Soc. 2015, 137, 7495-7501.

 

NO disproportionation in Fe-MOF-5

 

(25) Million-Fold Electrical Conductivity Enhancement in Fe2(DEBDC) versus Mn2(DEBDC) (E = S, O) - pdf
Sun, L.; Hendon, C. H.; Minier, M. A.; Walsh, A.; Dincă, M.
J. Am. Chem. Soc. 2015, 137, 6164-6167.

 

Electrical conductivity in MOF-74 analogs

 

(24) On the mechanism of MOF-5 formation under cathodic bias - pdf
Li, M.; Dincă, M.
Chem. Mater. 2015, 27, 3203-3206.

 

MOF-5 electrodeposition mechanism

 

(23) When the solvent locks the cage: theoretical insight into the transmetalation of MOF-5 lattices and its kinetic limitations - pdf
Bellarosa, L.; Brozek, C. K.; Garcia-Melchior; Dincă, M.; López, N.
Chem. Mater. 2015, 27, 3422-3429.

 

Computational mechanism of transmetalation in MOF-5

 

(22) Cu3(hexaiminotriphenylene)2: An Electrically Conductive 2D Metal–Organic Framework for Chemiresistive Sensing - pdf
Campbell, M. G.; Sheberla, D.; Liu, S.; Swager, T. M.; Dincă, M.
Angew. Chem. Int. Ed. 2015, 54, 4349-4352.

Read highlight by James Urquhart in Chemistry World

 

TTF MOFs with Tunable Conductivity

 

(21) Cation-Dependent Intrinsic Electrical Conductivity in Isostructural Tetrathiafulvalene-Based Microporous Metal-Organic Frameworks - pdf
Park, S. S.; Hontz, E. R.; Sun, L.; Hendon, C. H.; Walsh, A.; Van Voorhis, T.; Dincă, M.
J. Am. Chem. Soc. 2015, 137, 1774-1777.

 

TTF MOFs with Tunable Conductivity

 

(20) High Electrical Conductivity in Ni3(2,3,6,7,10,11-hexaiminotriphenylene)2, a Semiconducting Metal-Organic Graphene Analogue - pdf
Sheberla, D.; Sun, L.; Blood-Forsythe, M. A.; Er, S.; Wade, C. R.; Brozek, C. K.; Aspuru-Guzik, A.; Dincă, M.
J. Am. Chem. Soc. 2014, 136, 8859-8862.

Read media coverage of this work in Nature, C&E News, MIT News, IFL Science, IEEE Spectrum, and ScienceBlog, and DOE among others.

 

Semiconducting Metal-Organic Graphene Analog

 

(19) Cation Exchange at the Secondary Building Units of Metal-organic Frameworks - pdf
Brozek, C. K.; Dincă, M.
Chem. Soc. Rev. 2014, 43, 5456-5467.

 

Cation Exchange in MOFs

 

(18) Solvent-Dependent Cation Exchange in Metal-Organic Frameworks - pdf
Brozek, C. K.; Bellarosa, L.; Soejima, T.; Clark, T. V.; Lopez, N.; Dincă, M.
Chem.-Eur. J. 2014, 20, 6871-6874.

 

Solvent-dependent cation exchange in MOFs

 

(17) Ligand Redox Non-innocence in the Stoichiometric Oxidation of Mn2(2,5-dioxidoterephthalate) (Mn-MOF-74) - pdf
Cozzolino, A. F.; Brozek, C. K.; Palmer, R. D.; Yano, J.; Li, M.; Dincă, M.
J. Am. Chem. Soc. 2014, 136, 3334-3337.

 

Redox non-innocence in MOF-74

 

(16) Selective Formation of Biphasic Thin Films of Metal-Organic Frameworks by Potential-Controlled Cathodic Electrodeposition - pdf
Li, M.; Dincă, M.
Chem. Sci. 2014, 5, 107-111.

 

Bilayer MOF Thin Films Electrodeposition

 

(15) Selective Turn-On Ammonia Sensing Enabled by High-Temperature Fluorescence in Metal-Organic Frameworks with Open Metal Sites - pdf
Shustova, N. B.; Cozzolino, A. F.; Reineke, S.; Baldo, M.; Dincă, M.
J. Am. Chem. Soc. 2013, 135, 13326-13329.

 

Turn-On Ammonia Sensor Metal-Organic Framework

 

(14) Facile Deposition of Multicolored Electrochromic MOF Thin Films - pdf
Wade, C. R.; Li, M.; Dincă, M.
Angew. Chem., Int. Ed. 2013, 52, 13377-13381.

 

Electrochromic MOF Thin Films

 

(13) Ti3+-, V2+/3+-, Cr2+/3+-, Mn2+-, and Fe2+-Substituted MOF-5 and Redox Reactivity in Cr- and Fe-MOF-5 - pdf
Brozek, C. K.; Dincă, M.
J. Am. Chem. Soc. 2013, 135, 12886-12891.

 

Anomalous Dispersion for PSIM Ion-Exchange in MOFs

 

(12) Quantification of Site-Specific Cation Exchange in Metal-Organic Frameworks using Multi-Wavelength Anomalous X-ray Dispersion - pdf
Brozek, C. K.; Cozzolino, A. F.; Teat, S. J.; Cheng, Y.-S.; Dincă, M.
Chem. Mater. 2013, 25, 2998-3002.

 

Anomalous Dispersion for PSIM Ion-Exchange in MOFs

 

(11) Mn2(2,5-disulfhydrylbenzene-1,4-dicarboxylate): a Microporous MOF with Infinite (—Mn—S—) Chains and High Intrinsic Charge Mobility - pdf
Sun, L.; Miyakai, T.; Seki, S.; Dincă, M.
J. Am. Chem. Soc. 2013, 135, 8185-8188.

 

DSBDC MOFs with Infinite Mn-S Chains and High Charge Mobility

 

(10) Post-Synthetic Tuning of Hydrophilicity in Pyrazolate MOFs to Modulate Water Adsorption Properties - pdf
Wade, C. R.; Corrales-Sanchez, T.; Narayan, T.; Dincă, M.
Energy Environ. Sci. 2013, 6, 2172-2177.

 

Pyrazolate MOFs for Water Sorption and Adsorption Heat Pumps

 

(9) Thiophene-Based Covalent Organic Frameworks - pdf
Bertrand, G. H. V.; Michaelis, V. K.; Ong, T.-C.; Griffin, R. G.; Dincă, M.
Proc. Nat. Acad. Sci. USA 2013, 110, 4923-4928.

Article featured on the Cover Page of PNAS, March 26 2013

 

Conformational Locking in MOF

 

(8) Charge Transfer or J-Coupling? Assignment of an Unexpected Red-Shifted Absorption Band in a Naphthalenediimide-Based Metal-Organic Framework - pdf
McCarthy, B. D.; Hontz, E. R.; Yost, S. R.; Van Voorhis, T.; Dincă, M.
J. Phys. Chem. Lett. 2013, 4, 453-458.

 

Conformational Locking in MOF

 

(7) Conformational Locking by Design: Relating Strain Energy with Luminescence and Stability in Rigid Metal-Organic Frameworks - pdf
Shustova, N. B.; Cozzolino, A. F.; Dincă, M.
J. Am. Chem. Soc. 2012, 134, 19596-19599.

 

Conformational Locking in MOF

 

(6) Phenyl Ring Dynamics in a Tetraphenylethylene-Bridged Metal-Organic Framework: Implications for the Mechanism of Aggregation-Induced Emission - pdf
Shustova, N. B.; Ong, T.-C.; Cozzolino, A. F.; Michaelis, V. K.; Griffin, R. G.; Dincă, M.
J. Am. Chem. Soc. 2012, 134, 15061-15070.

 

Mechanism of Aggregation-Induced Emission

 

(5) High Charge Mobility in a Tetrathiafulvalene-Based Microporous Metal-Organic Framework - pdf
Narayan, T. C.; Miyakai, T.; Seki, S.; Dincă, M.
J. Am. Chem. Soc. 2012, 134, 12932-12935.

Read the feature story in C&E News: "New MOFs are Conductive by Mitch Jacoby

Article covered in Synfacts by Tim Swager and Markrete Krekorian

 

Conductive TTF MOF

 

(4) Lattice-Imposed Geometry in Metal-Organic Frameworks: Lacunary Zn4O Clusters in MOF-5 Serve as Tripodal Chelating Ligands for Ni2+ - pdf
Brozek, C. K.; Dincă, M.
Chem. Sci. 2012, 3, 2110-2113.

 

Ion Metathesis in MOFs: Ni-MOF-5

 

(3) Investigation of the Synthesis, Activation, and Isosteric Heats of CO2 Adsorption of the Isostructural Series of Metal-Organic Frameworks M3(BTC)2
(M = Cr, Fe, Ni, Cu, Mo, Ru)
- pdf

Wade, C. R.; Dincă, M.
Dalton Trans. 2012, 41, 7931-7938.

- special issue editorial "New Talents: Americas" - Mindiola, D. J.; Arnold J.; Agapie, T.; Love, J.; Dincă, M. Dalton Trans.2012, 41, 7781-7781.

 

CO2 in HKUST-1

 

(2) Turn-On Fluorescence in Tetraphenylethylene-Based Metal-Organic Frameworks: an Alternative to Aggregation-Induced Emission - pdf
Shustova, N. B.; McCarthy B. D.; Dincă, M.
J. Am. Chem. Soc. 2011, 133, 20126-20129.

Article featured on MIT's Front Page News: "A glow of recognition" by David Chandler

 

Turn-ON Fluorescent MOFs

 

(1) Reductive Electrosynthesis of Crystalline Metal-Organic Frameworks - pdf
Li, M.; Dincă, M.
J. Am. Chem. Soc. 2011, 133, 12926-12929.

 

MOF Electrodeposition

 

PREVIOUS PUBLICATIONS

 

(21) Impact of Metal and Anion Substitutions on the Hydrogen Storage Properties of M-BTT Metal-Organic Frameworks - pdf
Sumida, K.; Stuck, D.; Mino, L.; Chai, J.-D.; Bloch, E. D.; Zavorotynska, E.; Murray, L. J.; Dincă, M.; Chavan, S.; Bordiga, S.; Head-Gordon, M.; Long, J. R.
J. Am. Chem. Soc. 2013, 135, 1083-1091.

 

(20) Neutron Scattering and Spectroscopic Studies of Hydrogen Adsorption in Cr3(BTC)2 - A Metal-Organic Framework with Exposed Cr2+ Sites - pdf
Sumida, K.; Her, J. H.; Dincă, M.; Murray, L. J.; Schloss, J. M.; Pierce, C. J.; Thompson, B. A.; FitzGerald, S. A.; Brown, C. M.; Long, J. R.
J. Phys. Chem. C 2011, 115, 8414–8421.

 

(19) Highly Selective and Reversible O2 Binding in Cr3(1,3,5-benzenetricarboxylate)2 - pdf
Murray, L. J.; Dincă, M.; Yano, J.; Chavan S.; Bordiga, S.; Brown, C. M.; Long, J. R.
J. Am. Chem. Soc. 2010, 132, 7856-7857.

 

(18) Structure and Valency of a Cobalt-Phosphate Water Oxidation Catalyst Determined by in situ X-ray Spectroscopy - pdf
Kanan, M. W.; Yano, J.; Surendranath Y.; Dincă, M.; Yachandra V. K.; Nocera, D. G.
J. Am. Chem. Soc. 2010, 132, 13692-13701.

 

(17) EPR Evidence for Co(IV) Species Produced During Water Oxidation at Neutral pH - pdf
McAlpin, J. G.; Surendranath, Y.; Dincă, M.; Stich, T. A.; Stoian, S. A.; Casey, W. H.; Nocera, D. G.; Britt, R. D.
J. Am. Chem. Soc. 2010, 132, 6882-6883.

 

(16) A Nickel-Based Water Oxidation Catalyst that Functions under Benign Conditions - pdf
Dincă, M.; Surendranath, Y.; Nocera, D. G.
Proc. Nat. Acad. Sci. USA 2010, 107, 10337-10341.

 

(15) Hydrogen Storage in Water-Stable Metal-Organic Frameworks Incorporating 1,3- and 1,4-Benzenedipyrazolate - pdf
Choi, H. J.; Dincă, M.; Dailly, A.; Long, J. R.
Energy Environ. Sci. 2010, 3, 117-123.

 

(14) Electrolyte-Dependent Electrosynthesis and Activity of Cobalt Based Water Oxidation Catalysts - pdf
Surendranath, Y.; Dincă, M.; Nocera, D. G.
J. Am. Chem. Soc. 2009, 131, 2615-2620.

 

(13) Hydrogen Storage in Metal-Organic Frameworks - pdf
Murray, L. J.; Dincă, M.; Long, J. R.
Chem. Soc. Rev. 2009, 38, 1294-1314.

 

(12) Structure and Charge Control in Metal-Organic Frameworks Based on the Tetrahedral Ligand Tetrakis(4-tetrazolylphenyl)methane - pdf
Dincă, M.; Dailly, A.; Long, J. R.
Chem. Eur. J. 2008, 14, 10280-10285.

 

(11) Broadly Hysteretic H2 Adsorption in the Microporous Metal-Organic Framework Co(1,4-benzenedipyrazolate) - pdf
Choi, H. J.; Dincă, M.; Long, J. R.
J. Am. Chem. Soc. 2008, 130, 7848-7850.

 

(10) Hydrogen Storage in Microporous Metal-Organic Frameworks with Exposed Metal Sites - pdf
Dincă, M.; Long, J. R.
Angew. Chem. Int. Ed. 2008, 47, 6766-6779.

 

(9) Size-Selective Lewis-Acid Catalysis in a Microporous Metal-Organic Framework with Exposed Mn2+ Coordination Sites - Link
Horike, S.; Dincă, M.; Tamaki, K.; Long, J. R.
J. Am. Chem. Soc. 2008, 130, 5854-5855.

 

(8) Synthesis and Characterization of the Cubic Coordination Cluster [CoIII6CoII2(IBT)12]14- (H3IBT = 4,5-bis(tetrazol-5-yl)imidazole) - pdf
Dincă, M.; Harris, T. D.; Iavarone, A. T.; Long, J. R.
J. Mol. Struct. 2008, 890, 139-143.

 

(7) Expanded Sodalite-Type Metal-Organic Frameworks: Increased Stability and H2 Adsorption through Ligand-Directed Catenation - pdf
Dincă, M.; Dailly, A.; Tsay, C.; Long, J. R.
Inorg. Chem. 2008, 47, 11-13.

 

(6) High-Enthalpy Hydrogen Adsorption in Cation-Exchanged Variants of the Microporous Metal-Organic Framework Mn3[(Mn4Cl)3(BTT)8(CH3OH)10]2 - Link
Dincă, M.; Long, J. R.
J. Am. Chem. Soc. 2007, 129, 11172-11176.

 

(5) Observation of CuII-H2 Interactions in a Fully-Desolvated, Sodalite-Type Metal-Organic Framework - pdf
Dincă, M.; Han, W. S.; Liu, Y.; Dailly, A.; Brown, C. M.; Long, J. R.
Angew. Chem. Int. Ed. 2007, 46, 1419-1422.

 

(4) Hydrogen Storage in a Metal-Organic Framework with Exposed Mn2+ Coordination Sites - Link
Dincă, M.; Dailly, A.; Liu, Y.; Brown, C. M.; Neumann, D. A.; Long, J. R.
J. Am. Chem. Soc. 2006, 128, 16876-16883.

 

(3) Microporous Metal-Organic Frameworks Incorporating 1,4-Benzeneditetrazolate: Syntheses, Structures, and Hydrogen Storage Properties - pdf
Dincă, M.; Yu, A. F.; Long, J. R.
J. Am. Chem. Soc. 2006, 128, 8904-8913.

 

(2) Strong H2 Binding and Selective Gas Adsorption within the Three-dimensional Coordination Solid Mg3(O2C-C10H6-CO2)3 - pdf
Dincă, M.; Long, J. R.
J. Am. Chem. Soc. 2005, 127, 9376-9377.

 

(1) 9,10-dibromotriptycene - pdf
Abergel, R. J.; Dincă, M.
Acta Crystallogr. 2004, E60, o1248-o1249.